Home
Class 11
CHEMISTRY
The configuration of Cr atom is 3d^(5)4s...

The configuration of Cr atom is `3d^(5)4s^(1)` but not `3d^(4)4s^(2)` due to reason `R_(1)` and the configuration of Cu atom is `3d^(10)4s^(1)` but not `3d^(9)4s^(2)` due to reason `R_(2).R_(1) and R_(2)` are:

A

`R_(1):` The exchange energy of `3d^(5)4s^(1)`: is greater than that of `3d^(4)4s^(2)`
`R_(2):` The exchange energy of `3d^(10)4s^(1)` is greater than that of `3d^(9)4s^(2)`.

B

`R_(1)`: `3d^(5)4s^(1)` and `3d^(4)4s^(2)` have same exhange energy but `3d^(5)4s^(1)` is spheriaclly symmetrical.
`R_(2)`: `3d^(10)4s^(1)` is also shpherically symmetrical.

C

`R_(1)`: `3d^(5)4s^(1)` has grater exhange energy than `3d^(4)4s^(2)`.
`R_(2):3d^(10)4s^(1)` has spherical symmetry.

D

`R_(1):3d^(5)4s^(1)` has greater energy than `3d^(4)4s^(2)`.
`R_(2):3d^(10)4s^(1)` has greater energy than `3d^(9)4s^(2)`.

Text Solution

Verified by Experts

The correct Answer is:
C


`3d^(5)4s^(1)` is correct because it has greater exchange possibilities of unpaired electron.
`3d^(10)4s^(1)` is correct because `3d^(10)` orbitals are spherically symmetrical.
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    OP TANDON|Exercise Assertion Reason|22 Videos
  • ATOMIC STRUCTURE

    OP TANDON|Exercise Matrix matching Type Question|5 Videos
  • ATOMIC STRUCTURE

    OP TANDON|Exercise Set-2|46 Videos
  • AROMATIC HYDROCARBONS (ARENES)

    OP TANDON|Exercise EXAMPLES|24 Videos
  • CHARACTERISATION OF ORGANIC COMPOUNDS

    OP TANDON|Exercise Passage-2|5 Videos

Similar Questions

Explore conceptually related problems

The electronic configuration of valence shell of Cu is 3d^(10)4s^(1) and not 3d^(9)4s^(2) . How is this configuration explained?

The element with electronic configuration 3d^(5)4s^(1) is

Electronic configuration of M^(3+) is [Ar]3d^(10)4s^(2) , it belongs to

Identify the atom which has ground state configuration [Ar]3d^(10)4s^(2)4p^(1)

Statement-1 : The groundstate configuration of Cr is [Ar] 3d^(5) 4s^(1) Statement-2 : The energy of atom is lesser in 3d^(5)4s^(1) configuration compared to 3d^(4)4s^(2) configuration.

Knowledge Check

  • Outer configuration of X is 3d^(5)4s^(1) . It belongs to group number

    A
    16
    B
    15
    C
    5
    D
    6
  • The element with electronic configuration 3d^(5)4s^(1) is

    A
    metalloid
    B
    non-metal
    C
    transition element
    D
    metal
  • Electronic configuration of M^(3+) is [Ar]3d^(10)4s^(2) , it belongs to

    A
    s-block
    B
    p-block
    C
    d-block
    D
    f-block
  • OP TANDON-ATOMIC STRUCTURE -Objective Question Level-B
    1. The configuration of Cr atom is 3d^(5)4s^(1) but not 3d^(4)4s^(2) due ...

      Text Solution

      |

    2. Which of the following graphs is incorrect?

      Text Solution

      |

    3. Which among the following is correct of .(5)B in normal state?

      Text Solution

      |

    4. Maximum value (n+l+m) for unpaired electrons in second excited state o...

      Text Solution

      |

    5. Which of the following is correctly matched?

      Text Solution

      |

    6. In Bohr series of lines of hydrogen spectrum, third line from the red ...

      Text Solution

      |

    7. In which of the following pairs is the probability of finding the elec...

      Text Solution

      |

    8. The orbital diagram in which both the Pauli's exlusion principle and H...

      Text Solution

      |

    9. The distance between 3rd and 2nd bohr orbits of hydrogen atom:

      Text Solution

      |

    10. Which diagram best represnts the apperance of the line spectrum of ato...

      Text Solution

      |

    11. The 'm' vlaue for an electron in an atom is equal to the number of m v...

      Text Solution

      |

    12. For a sub-shell with azimuthal quantum number 'l', the total values of...

      Text Solution

      |

    13. What are the values of the orbital angular momentum of an electron in ...

      Text Solution

      |

    14. After np orbitals are filled, the next orbital filled will be :- (a)...

      Text Solution

      |

    15. The ratio of (E(2) - E(1)) to (E(4) - E(3)) for He^(+) ion is approxim...

      Text Solution

      |

    16. Which of the following electronic configurations has zero spin multipl...

      Text Solution

      |

    17. The energy required for removal of electron fro 3s,3p,3d subshells of ...

      Text Solution

      |

    18. Which of the following electronic configuration have the highest excha...

      Text Solution

      |

    19. In a historical experiment to dtermine Planck's constant, a metal surf...

      Text Solution

      |

    20. Angular distribution functions of all orbitals have:

      Text Solution

      |