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C-Cl bond has partial double bondcharact...

C-Cl bond has partial double bondcharacter in

A

Vinyl chloride

B

Chlorobenzene

C

Both

D

None

Text Solution

Verified by Experts

The correct Answer is:
C
C-Cl bond has partial double bond character both in vinyl chloride and chlorobenzene due to resonane.
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In which of the following case central atom-F bond has partial double bond character?

Assertion: Aryl undergoes nucleophilic substitution with ease Reason The carbon halogen bond in aryl halides has partial double bond character .

In a substance that are resonance hybirds, the measured length of given bond usually differs form that predicted form any one of the contributing sturctures. Chloroethylene is found by measurement to have a C-Cl distance of 1.69A. This is shorter than C-Cl bond in such compounds a methly chloride (1.77A), an indication that in chloroethylene C-Cl bond has some double bond character. Which of the following has shortest C-Cl bond?

Assertion: Aryl halides undergo nucleophilic substitution reactions with ease. Reason:The carbon halogen bond in aryl halides has partial double bonds character.

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Knowledge Check

  • In haloarenes C-Cl bond has partial double bond character, which is due to

    A
    inductive effect
    B
    electromertic
    C
    resonance
    D
    steric effect

  • In which of the following case central atom-F bond has partial double bond character?

    A
    `NF_3`
    B
    `CF_4`
    C
    `PF_3`
    D
    `OF_2`

  • Assertion: Aryl undergoes nucleophilic substitution with ease Reason The carbon halogen bond in aryl halides has partial double bond character .

    A
    If the the assertion and reason are true and reason is a true explanation of the assertion .
    B
    If both assertion and reason are true but reason is not the correct explanation of the assertion .
    C
    If the assertion is true but reason is true
    D
    If assertion is false but reason is true .
    • DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -UNIT TEST - 5
    1. C-Cl bond has partial double bondcharacter in

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    2. Which one is not true for all the members of a homologous series

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    3. The number of secondary atoms in the following compounds are CH(3)un...

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    4. The alkane which has only primary hydrogen atoms is

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    5. Which of the following compounds have isopropyl group

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    6. The IUPAC name of following compound is {:(CH(2)=C-CH(2)-CH(3)),(" ...

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    7. The IUPAC name of is

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    8. The IUPAC name of the compound is

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    9. The IUPAC name of the followin poly functional

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    10. Assingn the IUPAC name to the following compound

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    11. The IUPAC name of

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    12. Mistake in the name but-1-ene ol is

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    13. Racemic mixture is formed ny mixing two:

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    14. Geometrical isomerism is not shon by

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    15. Among the following four structures I to IV I {:(" "CH(3))...

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    16. Which of the following compounds will show meso isomer ?

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    17. Which of the following compounds will show metamerism ?

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    18. Correct order of nucleophilicity is

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    19. The basic strength of underset(I)(CH-=C), underset(II)(CH(2)=CH), un...

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    20. Consider the following carbanions Correct order of stability is

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    21. Different hydrogen in overset(a)(C )H(3)overset(b)(C )H=overset(b)(C...

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