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When pentan-2-one is oxidised using conc...

When pentan-2-one is oxidised using conc. `HNO_(3)`, the major products formed will be

A

n-Butyric acid and Formic acid

B

Isobutyric acid and Acetic acid

C

Pentanoic acid

D

Ethanoic acid and Propanoic acid.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of what major products are formed when pentan-2-one is oxidized using concentrated HNO3, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Pentan-2-one**: - Pentan-2-one has a 5-carbon chain with a ketone (C=O) group at the second carbon position. - The structure can be represented as: ``` CH3-CO-CH2-CH2-CH3 ``` 2. **Understand the Oxidation Reaction**: - When pentan-2-one is oxidized with concentrated nitric acid (HNO3), it acts as a strong oxidizing agent. - The ketone group (C=O) can be oxidized to form a carboxylic acid. 3. **Determine the Products of Oxidation**: - The oxidation of the ketone group at the second carbon will lead to the formation of a carboxylic acid. - The alkyl chain (the rest of the carbon chain) will also undergo oxidation, resulting in another carboxylic acid. 4. **Identify the Carboxylic Acids Formed**: - The oxidation of the ketone group (C=O) at the second position will yield: - From the ketone (2 carbon atoms): Ethanoic acid (CH3COOH). - The oxidation of the remaining carbon chain (3 carbon atoms) will yield: - From the alkyl chain (3 carbon atoms): Propanoic acid (C2H5COOH). 5. **Final Products**: - Therefore, the major products formed from the oxidation of pentan-2-one using concentrated HNO3 are: - Ethanoic acid (CH3COOH) - Propanoic acid (C2H5COOH) 6. **Conclusion**: - The correct answer is that the major products are Ethanoic acid and Propanoic acid.

To solve the question of what major products are formed when pentan-2-one is oxidized using concentrated HNO3, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Pentan-2-one**: - Pentan-2-one has a 5-carbon chain with a ketone (C=O) group at the second carbon position. - The structure can be represented as: ``` ...
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Knowledge Check

  • When pentan-2-one is oxidised using conc. HNO_(3) the major product will be

    A
    `n-`Butyric acid and formic acid
    B
    Isobutyric acid and acetic acid
    C
    Pentanoic acid
    D
    Ethanoic acid
  • When hexan-2-one is oxidised using conc. HNO_(3) , the major product will be

    A
    n-Butyric acid and acetic acid
    B
    Isobutyric acid and acetic acid
    C
    Pentanoic acid
    D
    Ethanoic acid.
  • When table sugar is heated conc. HNO_3 , the product formed is

    A
    sucrose nitrate
    B
    adipic acid
    C
    oxalic acid
    D
    citric acid
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