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Chemical equilibrium is attained in a re...

Chemical equilibrium is attained in a reversible reaction carried in a close container and is of dynamic nature. The value of equilibrium constant may be expressed either as `K_(p)" and " K_(c)` and the two are related to each other as :
`K_(p) =K_(c)(RT)^(Deltang)`
Free energy change `(DeltaG)` at equilibrium point is zero. The value of equilibrium constant gives the extent to which a particular reation has proceeded to attain the equilibrium . Its value gets reversed if the reaction is reversed and becomes the square root of the initial value if the reaction is divided by 2.
when the two reactants A and B are mixed to give products C and D , the reaction quotient Q at initial stage of the reaction:

A

is zero

B

decreases with time

C

is independent of time

D

increases with time

Text Solution

Verified by Experts

The correct Answer is:
D

`Q=[[C][D]]/[[A][B]]`
Since the molar concentration of products increases while that of the reactants decreases the value of Q increases with time.
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Knowledge Check

  • Chemical equilibrium is attained in a reversible reaction carried in a close container and is of dynamic nature. The value of equilibrium constant may be expressed either as K_(p)" and " K_(c) and the two are related to each other as : K_(p) =K_(c)(RT)^(Deltang) Free energy change (DeltaG) at equilibrium point is zero. The value of equilibrium constant gives the extent to which a particular reation has proceeded to attain the equilibrium . Its value gets reversed if the reaction is reversed and becomes the square root of the initial value if the reaction is divided by 2. A reaction attains equilibrium when the free energy change accompanying the reaction is :

    A
    Positive and large
    B
    Zero
    C
    Negative
    D
    Negative and small.
  • Chemical equilibrium is attained in a reversible reaction carried in a close container and is of dynamic nature. The value of equilibrium constant may be expressed either as K_(p)" and " K_(c) and the two are related to each other as : K_(p) =K_(c)(RT)^(Deltang) Free energy change (DeltaG) at equilibrium point is zero. The value of equilibrium constant gives the extent to which a particular reation has proceeded to attain the equilibrium . Its value gets reversed if the reaction is reversed and becomes the square root of the initial value if the reaction is divided by 2. For the reaction PCI_(3)(g)+ CI_(2) (s) hArr PCI_(5) (g) The value of k_(c) " at " 250^(@)C " is " " mol"^(-1) L^(-1) . The value of k_(p) at the same temperature will be :

    A
    `0.61 atm^(-1)`
    B
    `0.56 atm^(-1)`
    C
    `0.83 atm^(-1)`
    D
    `0.46 atm^(-1)`
  • Standard free energy change for an equilibrium is zero, the value of K_(p) is

    A
    zero
    B
    1
    C
    2
    D
    100
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