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In the button cell, widely used in watch...

In the button cell, widely used in watches, the following reaction takes place
`Zn(s)+Ag_(2)O(s)+H_(2)O to Zn^(2+)(aq)+2Ag(s)+2OH^(-)(aq)`
Determine `E^(@)` and `DeltaG^(@)` for the reaction.
(Given : `E_(Ag^(+)//Ag)^(@)=+0.80 V,E_(Zn^(2+)//Zn)^(@)=-0.76 V`

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AI Generated Solution

To determine the standard cell potential \( E^\circ \) and the standard Gibbs free energy change \( \Delta G^\circ \) for the reaction given in the button cell, we can follow these steps: ### Step 1: Identify the Half-Reactions The overall reaction is: \[ \text{Zn(s)} + \text{Ag}_2\text{O(s)} + \text{H}_2\text{O} \rightarrow \text{Zn}^{2+}(aq) + 2\text{Ag(s)} + 2\text{OH}^-(aq) \] ...
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(a) What type of a battery is the lead storage battery ? Write the anode and the cathode reactions and the overall occuring in a lead storage battery when current is drawn from it. (b) In the buttom cell, widely used in watches the following reaction take place Zn_((s)) + Ag_(2)O_((l)) rarr Zn^(2+)(aq) + 2Ag_((s)) + 2OH_((aq))^(-) . Determine E^(@) and DeltaG^(@) for the reaction. (given : E_(Ag^(+)//Ag)^(@) = +0.80 V , E_(Zn^(2+)//Zn)^(@) = - 0.76 V)

In the button cells widely used in watCHMes and other devices the following reaction takes place : Zn(s)+Ag_(2)O(s)+H_(2)O(l) rarr Zn^(2+)(aq)+2Ag(s)+2OH^(c-)(aq) Determine Delta_(r)G^(c-) and E^(c-) for the reaction.

In the button cells widely used in watches and other devices the following reaction takes place: Zn(s) + Ag_(2)O(s) + H_(2)O (l) to Zn^(2+) (aq) + 2Ag(s) + 2OH^(-)(aq) Determine DeltaG^(@) and E^(@) for the reaction Zn(s) to Zn^(2+) + 2e^(-) , E^(@) = 0.76 V Ag_(2)O + H_(2)O + 2e^(-) to 2Ag + 2OH^(-) E^(@) = +0.34 V

Calculate Delta_(r)G^(@) and e.m.f. (E) that can be obtained from the following cell under the standard conditions at 25^(@)C: Zn(s)|Zn^(2+)(aq)" "Sn^(2+)(aq)|Sn(s) Given E_(Zn^(2+)//Zn)^(@)=-0.76V,E_(Sn^(2+)//Sn)^(@)=-0.14V And F=96500C" "mol^(-1) OR (a) Define conductivity and molar conductivity for the solution of an electrolyte. Discuss their variation with concentration. (b) Calculation the standard cell potential of the galvanic cell in which the following reaction takes place: Fe^(2+)(aq)+Ag^(+)(aq)toFe^(3+)(aq)+Ag(s) Calculate the Delta_(r)G^(@) and equilibrium constant of the reaction also. (E_(Ag^(+)//Ag)^(@)=0.80,E_(Fe^(3+)//Fe^(2+))^(@)=0.77V)

Consider Delta G^(@) for the following cell reaction : Zn (s) + Ag_(2)O(s)+H_(2)O(l) hArr Zn^(2+)(aq)+2Ag(s)+2OH^(-)(aq) E_(Ag^(+)//Ag)^(@) = +0.80 and E_(Zn^(2+)//Zn)^(@) = - 0.76 V

Delta_rG^@ for the cell with the cell reaction : Zn_((s))+ Ag_2O_((s)) + H_2O_((l)) to Zn_((aq))^(2+) + 2Ag_((s)) + 2OH_((aq))^(-) [E_(Ag_2O // Ag)^(@)=0.344 V, E_(Zn^(2+)//Zn)^@=-0.76 V]

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