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How would you determine the standard reduction potential of the system `Mg^(2+)|Mg`?

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In order to determine `E^(@)` value of `Mg^(2+)//Mg` electrode, an electrochemical cell is set up in which a Mg electrode dipped in 1 M `MgSO_(4)` solution acts as one half cell (oxidation half cell) while the standard hydrogen electrode acts as the other half cell (reduction half cell). The deflection of voltmeter placed in the cell circuit is towards the Mg-electrode indicating the flow of current. The cell may be represented as :
`Mg//Mg^(2+)(1 M)|| H^(+)(1 M)//H_(2)(1 atm)`,
The reading as given by voltmeter gives `E_(cell)^(@)`
`E_(cell)^(@)=E_(H^(+)//1//2H_(2))^(@)-E_(Mg^(2+)//Mg)^(@)=0-E_(Mg^(2+)//Mg)^(@)`
The expected value of standard electrode potential (`E^(@)`)=-2.36 V`.
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Knowledge Check

  • Standard reduction potential is calculated at

    A
    `27^(@)C`
    B
    `25^(@)C`
    C
    `0^(@)C`
    D
    `100^(@)C`
  • Standard reduction potential of an element equal to

    A
    `+ 1 xx` its reduction potential
    B
    `- 1 xx ` its standard oxidation potential
    C
    `0.00`V
    D
    `+ 1 xx ` its standard oxidation potential
  • The first ionization potential of Mg is

    A
    less than Al
    B
    more than Al
    C
    equal to Al
    D
    can be less or more than Al
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