Match column I and column II
`{:( "((A)Ammolysis", " (p) Amine with lesser no. of carbon atom") , ("(B) Gabriel phthalimide " , "(q) Detection of primary amine"),(" (C)Hoffmann bromide amide degradation" , "(r) Reaction of pthalimide with KOH and R-X") , ( "(D)Carbylamine reaction" , " (s) Reaction of alkyl halides with" NH_(3)):}`

Options

A. A-s, B-r, C-p, D-q
B. A-p, B-q, C-r, D-s
C. A-r, B-s, C-p, D-q
D. A-s, B-r, C-q, D-p

Answer

To solve the matching question, we need to analyze each item in Column I and find the corresponding item in Column II based on the definitions and reactions associated with each term.

### Step-by-Step Solution:

1. **Identify Ammonolysis (A)**:
- Ammonolysis refers to the reaction of an alkyl halide with ammonia (NH₃) to form an amine.
- In Column II, the option that describes this reaction is (s) "Reaction of alkyl halides with NH₃".
- **Match**: A → s

2. **Identify Gabriel Phthalimide (B)**:
- The Gabriel phthalimide synthesis involves the reaction of phthalimide with an alkyl halide in the presence of a base (usually KOH) to produce a primary amine.
- In Column II, the corresponding option is (r) "Reaction of phthalimide with KOH and R-X".
- **Match**: B → r

3. **Identify Hoffmann Bromamide Degradation (C)**:
- The Hoffmann bromamide degradation involves the conversion of an amide to a primary amine using bromine (Br₂) and a base (usually NaOH).
- This reaction typically results in the formation of an amine with a lesser number of carbon atoms than the original amide.
- In Column II, the correct match is (p) "Amine with lesser no. of carbon atom".
- **Match**: C → p

4. **Identify Carbylamine Reaction (D)**:
- The carbylamine reaction is used for the detection of primary amines. When a primary amine reacts with chloroform (CHCl₃) in the presence of a base, it produces a foul-smelling isocyanide.
- In Column II, the corresponding option is (q) "Detection of primary amine".
- **Match**: D → q

### Final Matches:
- A → s
- B → r
- C → p
- D → q