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While sulphur dioxide and hydrogen perox...

While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reaction ozone and nitric acid act only as oxidatns .Why ?

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A species can act as both oxidant and reductant if any one of its constitument atoms has an intermediate value of oxidation number .So in a reaction the atom can increase or decrease its oxidation number i.e it can acts as an oxidation as well as a reductant.
In `SO_(2)`the oxidation number of S is +4 .The highest and lowest oxidation numbers of S are +6 and -2 respectively .Therefore , S - atoms in `SO_(2)` is able to increase its oxidation number in a reaction in which `SO_(2)` acts as a reductant and decrease its oxidation number in a reaction in which `SO_(2)` plays a role of an oxidation .Hence,`SO_(2)` can acts as an oxidant as well as a reductant.
2 In `H_(2)O_(2)` ,the oxidation number of O is -1 The highest and lowest oxidation numbers of oxygen are -2 and 0 respectively .Therefore,oxygen atom in `H_(2)O_(2)` is capable of increasing or decreasing its `H_(2)O_(2)` is capable of increasing or decreasing its oxidation number .The reaction in which` H_(2)O_(2)`acts as an oxidant ,the oxidation number of oxygen decreases from -1 to -2 and the reaction in which it acts as a reduction ,the oxidation number of oxygen increases from -1 to 0 .Hence `H_(2)O_(2)` can acts both as an oxidant and a reductant.
3 In `O_(3)` ,the oxidation number of oxygen is zero. Oxygen can show two oxidation number -1 and -2 . So, the oxidation number of oxygen in `O_(3)` can reduce to -1 or -2 but in can never increases .Hence ,`O_(3)` can act only as an oxidant.
4 In `HNO_(3)` ,the oxidation number of nitrogen is +5 .It is the maximum oxidation number that nitrogen can exhibit .So the Only opportunity for nitrogen in `HNO_(3)` is to decrease its oxidation number .Hence `HNO_(3)` can act only as an oxidant .
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Knowledge Check

  • The compound which acts as an oxidising as well as a reducing agent is-

    A
    `NaNO_3`
    B
    `Na_2O`
    C
    `Na_2O_2`
    D
    `KNO_3`
  • Which can act as an acid as well as a base-

    A
    `SO_4^(2-)`
    B
    `HS^-`
    C
    `HCO_3^-`
    D
    `HSO_4^-`
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