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Explain the bonding in coordination compounds in terms of Werner’s postulates.

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Knowledge Check

  • Complex compounds are molecular compounds which retain their indentities even when dissolved in water. They do not give all the simple ions in solution but instead furnish complex ions. The complex compounds are often called coordination compounds because certain groups called ligands are attached to the central metal ion by coordinate or dative bonds. Coordination compounds exhibit isomerism, both structural and stereoisomerism. The struculre, magnetic property, colour and electrical properties of complexes are explained by various theories. which of the following pairs, both the complexes have the same geometry?

    A
    `[NiCl_(4)]^(2-),[Ni(CN)_(4)]^(2-)`
    B
    `[CoF_(6)]^(3-),[Co(NH_(3))_(6)]^(3+)`
    C
    `[Ni(CO)_(4)],[Ni(CN)_(4)]^(2-)`
    D
    `[Cu(NH_(3))_(4)]^(+),[Ni(NH_(3))_(4)]^(2+)`
  • Complex compounds are molecular compounds which retain their indentities even when dissolved in water. They do not give all the simple ions in solution but instead furnish complex ions. The complex compounds are often called coordination compounds because certain groups called ligands are attached to the central metal ion by coordinate or dative bonds. Coordination compounds exhibit isomerism, both structural and stereoisomerism. The struculre, magnetic property, colour and electrical properties of complexes are explained by various theories. The oxidation number, coordination number and magnetic moment in the following complex Na_(3)[Cr(CN)_(6)] is :

    A
    `O.N=+3,C.N.=6,M.M.=sqrt(15)BM`
    B
    O.N = -1, C.N. = 6, M.M. = `sqrt(15)BM`
    C
    O.N = +3, C.N. = 6, M.M. = `sqrt(3)BM`
    D
    0,= +3, CN. = 6, MM. = `sqrt(12)BM`
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