Home
Class 11
CHEMISTRY
Identify the Aromatic compound in the fo...

Identify the Aromatic compound in the following

A

Tetra hydro furan

B

Pyridine

C

Cyclopenta dienyl anion

D

both 2 & 3

Text Solution

AI Generated Solution

The correct Answer is:
To identify the aromatic compound among the given options, we will follow these steps: ### Step 1: Understand the Criteria for Aromaticity A compound is considered aromatic if it meets the following criteria: 1. It is cyclic. 2. It is planar. 3. It follows Huckel's rule, which states that the compound must have \(4n + 2\) π electrons, where \(n\) is a whole number (0, 1, 2,...). ### Step 2: Analyze Each Compound #### Option A: Tetrahydrofuran - **Structure**: Tetrahydrofuran is a saturated compound derived from furan by hydrogenation. - **Hybridization**: All carbons are sp³ hybridized, meaning there are no π bonds. - **π Electrons**: Since there are no π bonds, there are no π electrons to delocalize. - **Conclusion**: Tetrahydrofuran is **not aromatic**. #### Option B: Pyridine - **Structure**: Pyridine is a six-membered ring with one nitrogen atom. - **Hybridization**: The carbon atoms are sp² hybridized, and there are three π bonds. - **π Electrons**: Each π bond contributes 2 π electrons, giving a total of \(3 \times 2 = 6\) π electrons. - **Huckel's Rule**: For \(n = 1\), \(4n + 2 = 6\). Thus, pyridine follows Huckel's rule. - **Conclusion**: Pyridine is **aromatic**. #### Option C: Cyclopentadienyl Anion - **Structure**: Cyclopentadienyl anion consists of a five-membered ring with two double bonds and a negative charge. - **Hybridization**: The carbons are sp² hybridized, and the negative charge contributes to the π system. - **π Electrons**: There are 4 π electrons from the two double bonds and 2 additional π electrons from the negative charge, totaling \(4 + 2 = 6\) π electrons. - **Huckel's Rule**: For \(n = 1\), \(4n + 2 = 6\). Thus, cyclopentadienyl anion follows Huckel's rule. - **Conclusion**: Cyclopentadienyl anion is **aromatic**. ### Step 3: Final Conclusion - **Option D**: The correct answer is that both **pyridine (Option B)** and **cyclopentadienyl anion (Option C)** are aromatic compounds. ### Summary The aromatic compounds among the given options are: - Pyridine (Option B) - Cyclopentadienyl anion (Option C)

To identify the aromatic compound among the given options, we will follow these steps: ### Step 1: Understand the Criteria for Aromaticity A compound is considered aromatic if it meets the following criteria: 1. It is cyclic. 2. It is planar. 3. It follows Huckel's rule, which states that the compound must have \(4n + 2\) π electrons, where \(n\) is a whole number (0, 1, 2,...). ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • HYDROCARBONS

    NARAYNA|Exercise EXERCISE - 1 (C.W) (PREPARATION & PROPERTIES)|5 Videos
  • HYDROCARBONS

    NARAYNA|Exercise EXERCISE - 1 (C.W) (DIRECTING INFLUENCE OF FUNCTIONAL GROUPS & CHEMICAL REACTIVITY)|2 Videos
  • HYDROCARBONS

    NARAYNA|Exercise EXERCISE - 1 (C.W) (PROPERTIES)|5 Videos
  • GENERAL ORGANIC CHEMISTRY

    NARAYNA|Exercise Matrix-Match type questions|7 Videos
  • HYDROGEN & ITS COMPOUCDS

    NARAYNA|Exercise Interger type questions|10 Videos

Similar Questions

Explore conceptually related problems

Identify the aromatic amino acid

The non aromatic compound among the following is -

Knowledge Check

  • Identity the aromatic compound from the following.

    A
    B
    C
    D
  • The non-aromatic compound among the following

    A
    B
    C
    D
  • Identify the aromatic amino acid

    A
    C-O
    B
    C-C
    C
    C-N
    D
    P-O.
  • Similar Questions

    Explore conceptually related problems

    The non aromatic compound among the following is :

    Identify the compound which is not aromatic :

    Identify the compounds that will undergo nucleophilic aromatic substitution reaction :

    Aromaticity order for the following aromatic compound will be

    Identify the compounds that give aromatic salt on reaction with HCIO_(4) :