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In a Friedel-Crafts reaction, the electr...

In a Friedel-Crafts reaction, the electrophile is:

A

`Cl^(-) or X^(-)`

B

`CH_(3)^(+)or CH_(3)CO^(+)`

C

`CH_(3)Cl`

D

`CH_(3)COCl`

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The correct Answer is:
To determine the electrophile in a Friedel-Crafts reaction, we need to understand the two types of Friedel-Crafts reactions: alkylation and acylation. ### Step-by-Step Solution: 1. **Understanding Friedel-Crafts Reactions**: - Friedel-Crafts reactions are electrophilic aromatic substitution reactions that involve the introduction of an alkyl or acyl group into an aromatic ring (like benzene). - There are two main types: Friedel-Crafts alkylation and Friedel-Crafts acylation. 2. **Friedel-Crafts Alkylation**: - In this reaction, benzene reacts with an alkyl halide (e.g., CH3Cl) in the presence of a Lewis acid (e.g., AlCl3). - The Lewis acid activates the alkyl halide to form a carbocation (alkyl cation), which is the electrophile. - For example, when CH3Cl reacts with AlCl3, it generates CH3^+ (methyl cation) as the electrophile. 3. **Friedel-Crafts Acylation**: - In this reaction, benzene reacts with an acyl halide (e.g., RCOCl) in the presence of a Lewis acid. - The reaction produces an acylium ion (RCO^+), which serves as the electrophile. - For example, RCOCl reacts with AlCl3 to produce RCO^+ (acylium ion), which can then react with benzene. 4. **Identifying the Electrophile**: - In Friedel-Crafts alkylation, the electrophile is the alkyl cation (e.g., CH3^+). - In Friedel-Crafts acylation, the electrophile is the acylium ion (e.g., RCO^+). - Therefore, the electrophile in a Friedel-Crafts reaction can be either CH3^+ or RCO^+ depending on the type of reaction. 5. **Conclusion**: - The correct answer to the question "In a Friedel-Crafts reaction, the electrophile is:" is option B, which includes both CH3^+ and RCO^+.
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OP TANDON-BASIC PRINCIPLES OF ORGANIC COMPOUNDS (MECHANISM OF ORGANIC REACTIONS)-OBJECTIVE QUESTIONS (Level-A)
  1. Addition of HBr to propene in presence of peroxide (antiMarkownikoff's...

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  2. A nucleophile must have :

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  3. In a Friedel-Crafts reaction, the electrophile is:

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  4. Arrange the following carbanions in decreasing orde of stability: HC...

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  5. Arrange the following carbocations in order of increasing stability : ...

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  6. Which one of the following behaves both as a nucleophile and an electr...

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  7. Consider the following bromides: The correct order of S(N^(1)) re...

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  8. Which one is the correct order of decreasing stability of car banions?

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  9. The stability order in the following carbocations, CH(3)CH(2)^(+)"(I...

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  10. Which one of the following carbocations is most stable?

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  11. Which is the weakest base of the following whose pK(b) val-use are?

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  12. Which is decreasing order of acidity in, HCOOH(I), CH(3)COOH(II), CH...

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  13. Which one of the following is the weakest base in queous medium ?

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  14. Which of the following compounds prossesses the C-H bonds with the low...

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  15. Which one of the following compounds is most acidic?

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  16. Arragne basicity of the following compounds in decreasing order: CH(...

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  17. Which is the increasing order of acidic strength in the following comp...

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  18. Which of the following compounds is not a Lewis acids?

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  19. Which of the following contains three pairs of electron?

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  20. In the following compounds phenol (I), p-cresol (II), m-nitrophenol (I...

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