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The magnetic moment for two complexes of...

The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and 2.84 BM respectively. The second complex is not a netural complex.
The number of water molecules of crystallization are respectively

A

zero, two

B

zero, zero

C

two, zero

D

two ,two

Text Solution

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The correct Answer is:
C
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The magnetic moment for two complexes of empirical formula Ni(NH_(3))_(4)(NO_(3))_(2)*2H_(2)O is zero and 2.84 BM respectively. The second complex is not a neutral complex. Q. Which of the following statements are true for the second complex ?

The magnetic moment of a complex ion is 2.83 BM. The complex ion is :

Knowledge Check

  • The magnetic moment for two complexes of empirical formula Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O is zero and 2.84 BM respectively. The second complex is not a netural complex. The correct formula and geometry of the first complex is :

    A
    `[Ni(H_(2)O)_(2)(NO_(3))_(2).4NH_(3)`,tetrahedral
    B
    `[Ni(NH_(3))_(4)](CO)_(3))_(2).2H_(2)O`,tetrahedral
    C
    `[Ni(NH_(3))_(4)](NO_(3))_(2).2H_(2)O`,square planar
    D
    `[Ni(NH_(3))_(4)](H_(2)O)_(2)](NO_(3))_(2)`, octahedral
  • The magnetic moment for two complexes of empirical formula Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O is zero and 2.84 BM respectively. The second complex is not a netural complex. Which of the following statement are true for the second complex ?

    A
    It has the EAN value of 36
    B
    It can show optical isomerism.
    C
    It cannot show geometrical isomerism.
    D
    It produces three-fold freezing point depression.
  • The magnetic moment for two complexes of empirical formula Ni(NH_(3))_(4)(NO_(3))_(2)*2H_(2)O is zero and 2.84 BM respectively. The second complex is not a neutral complex. Q. The correct formula and geometry of the first complex is:

    A
    `[Ni(H_(2)O)_(2)(NO_(3))_(2)]*4NH_(3)`, tetrahedral.
    B
    `[Ni(NH_(3))_(4)](NO_(3))_(2)*2H_(2)O`,tetrahedral.
    C
    `[Ni(NH_(3))_(4)](NO_(3))_(2)*2H_(2)O`,square planar
    D
    `[Ni(NH_(3))_(4)(H_(2)O)_(2)](NO_(3))_(2)`,octahedral.
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