Home
Class 11
CHEMISTRY
In a fuel cell methanol is oxidised with...

In a fuel cell methanol is oxidised with oxygen as : `CH_(3)OH(l) + 3/2O_(2)(g) to CO_(2)(g) + 2H_(2)O(l)`
Calculate the standard Gibbs energy change for the reaction that can be converted into electrical works. If standard enthalpy of combustion for methanol is `726 kJ mol^(-1)`, calculate the efficiency of conversion of Gibbs energy into useful work. The standard Gibbs energies of formation, `Delta_(f)G^(@)(kJ mol^(-1))` are :
`CO_(2)(g) = -394.4, H_(2)O(l) = -237.2, CH_(3)OH(l) = -166.2`.

Text Solution

AI Generated Solution

To solve the problem, we need to calculate the standard Gibbs energy change (ΔG) for the given reaction and then determine the efficiency of converting Gibbs energy into useful work. **Step 1: Write the reaction and identify the components.** The reaction given is: \[ \text{CH}_3\text{OH}(l) + \frac{3}{2}\text{O}_2(g) \rightarrow \text{CO}_2(g) + 2\text{H}_2\text{O}(l) \] **Step 2: Use the Gibbs energy of formation values to calculate ΔG.** The formula for calculating ΔG for the reaction is: ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    MODERN PUBLICATION|Exercise Practice Problems|65 Videos
  • THERMODYNAMICS

    MODERN PUBLICATION|Exercise Advanced Level Problems|15 Videos
  • STRUCTURE OF ATOM

    MODERN PUBLICATION|Exercise Unit Practice Test|13 Videos

Similar Questions

Explore conceptually related problems

In a fuel cell, methanol if used as fuel and oxygen gas is used as an oxidiser. The reaction is CH_(3)OH(l) +(3)/(2)O_(2)(g)rarrCO_(2)(g)+2H_(2)O(l) Calculated standard Gibbs free enegry change for the reaction that can be converted into electircal work. If standard enthalpy of combustion for methanol is -702 kJ mol^(-1) , calculate the efficiency of converstion of Gibbs energy into useful work. Delta_(f)G^(Theta) for CO_(2),H_(2)O, CH_(3)OH,O_(2) is -394.00, -237.00,-166.00 and 0 kJ mol^(-1) respectively.

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is : CH_(3)OH_((l))+(3)/(2)O_(2(g))rarr CO_((g))+2H_(2)O_((l)) At 298K standard Gibb's energies of formation for CH_(3)OH(l), H_(2)O(l) and CO_(2)(g) are -166.2,-237.2 and -394.4kJ mol^(-1) respectively. If standard enthalpy of combustion of methanol is -726kJ mol^(-1) , efficiency of the fuel cell will be :

For the water gas reaction C(s) + H_(2)O(g) hArr CO(g) + H_(2)(g) At 1000K , the standard Gibbs free energy change of the reaction is -8.314KJ//mol . Therefore, at 1000K the equilibrium constant of the above water gas reaction is