Home
Class 11
CHEMISTRY
2-Bromopentane is treated with alcoholic...

2-Bromopentane is treated with alcoholic KOH solution. The major product formed in this reaction and the type of reaction respectively are

A

pent-2-ene, `beta`-elimination

B

pent-l-ene, `beta`-elimination

C

pentan-2-ol, nucleophilic substitution

D

pent-1-ene, nucleophilic substitution

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of what major product is formed when 2-Bromopentane is treated with alcoholic KOH, let's break down the reaction step by step. ### Step 1: Identify the Reactants We start with 2-Bromopentane, which has the following structure: - **Structure**: CH3-CH2-CHBr-CH2-CH3 ### Step 2: Understand the Role of Alcoholic KOH Alcoholic KOH is a strong base and will promote elimination reactions (dehydrohalogenation) rather than substitution reactions. The hydroxide ion (OH-) acts as a base to abstract a proton (H+) from the adjacent carbon atom. ### Step 3: Mechanism of the Reaction 1. The KOH will abstract a proton from the carbon adjacent to the carbon bearing the bromine atom (the β-carbon). 2. This results in the formation of a double bond (alkene) and the elimination of bromide ion (Br-). ### Step 4: Determine Possible Products When 2-Bromopentane undergoes elimination: - If the proton is removed from the carbon adjacent to the carbon with Br (C-3), the product will be: - **Product 1**: CH3-CH=CH-CH2-CH3 (2-pentene) - If the proton is removed from the other adjacent carbon (C-2), the product will be: - **Product 2**: CH3-CH2-CH=CH-CH3 (1-pentene) ### Step 5: Stability of the Alkenes To determine which alkene is the major product, we assess the stability of the alkenes formed: - 2-pentene (Product 1) has more alkyl substituents around the double bond, making it more stable due to hyperconjugation and the inductive effect. - 1-pentene (Product 2) is less stable as it has fewer substituents. ### Step 6: Conclusion The major product formed is **2-pentene**, and the type of reaction is **β-elimination** (also known as dehydrohalogenation). ### Final Answer The major product formed is **2-pentene**, and the type of reaction is **β-elimination**. ---

To solve the problem of what major product is formed when 2-Bromopentane is treated with alcoholic KOH, let's break down the reaction step by step. ### Step 1: Identify the Reactants We start with 2-Bromopentane, which has the following structure: - **Structure**: CH3-CH2-CHBr-CH2-CH3 ### Step 2: Understand the Role of Alcoholic KOH Alcoholic KOH is a strong base and will promote elimination reactions (dehydrohalogenation) rather than substitution reactions. The hydroxide ion (OH-) acts as a base to abstract a proton (H+) from the adjacent carbon atom. ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • HYDROCARBONS

    MODERN PUBLICATION|Exercise COMPETITION FILE (OBJECTIVE TYPE QUESTIONS) (MULTIPLE CHOICE QUESTIONS from competitive examinations (JEE (Main) and Other State Boards. Engineering Entrance))|50 Videos
  • HYDROCARBONS

    MODERN PUBLICATION|Exercise COMPETITION FILE (OBJECTIVE TYPE QUESTIONS) (MULTIPLE CHOICE QUESTIONS from competitive examinations (JEE (Advance) for IIT Entrance))|4 Videos
  • HYDROCARBONS

    MODERN PUBLICATION|Exercise COMPETITION FILE (OBJECTIVE TYPE QUESTIONS) (MULTIPLE CHOICE QUESTIONS WITH ONLY ONE CORRECT ANSWER)|45 Videos
  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|12 Videos
  • HYDROGEN

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST (for Board Examination)|9 Videos

Similar Questions

Explore conceptually related problems

The major product formed in the reaction

The major product formed in the reaction is

Knowledge Check

  • The major product formed in the reaction:

    A
    B
    C
    D
  • The major product formed in the reaction:

    A
    B
    C
    D
  • The major product formed in the reaction:

    A
    B
    C
    D
  • Similar Questions

    Explore conceptually related problems

    The major product formed in the reaction is

    The major product formed in the reaction is

    The major product formed in the reaction is

    The major product formed in the reaction is:

    The major product formed in the reaction is: