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A : Phenol does not react with NaHCO(3) ...

A : Phenol does not react with `NaHCO_(3)` .
R : Phenol is less acidic than `H_(2)CO_(3)`

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question, we will break down the information step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "Phenol does not react with NaHCO3." - To evaluate this, we need to understand the nature of phenol and NaHCO3. NaHCO3 (sodium bicarbonate) is a weak base and can react with acids to form carbon dioxide, water, and a salt. 2. **Understanding the Reaction**: - For a reaction to occur between phenol and NaHCO3, phenol must be acidic enough to donate a proton (H⁺) to NaHCO3. - If phenol is less acidic than the acid that NaHCO3 can produce (which is carbonic acid, H2CO3), then phenol will not react. 3. **Analyzing the Reason**: - The reason states that "Phenol is less acidic than H2CO3." - This is indeed true. H2CO3 is a stronger acid compared to phenol. Therefore, phenol cannot donate a proton to NaHCO3 because H2CO3 would prefer to remain in its acidic form rather than dissociate. 4. **Conclusion**: - Since phenol does not react with NaHCO3 due to its lower acidity compared to H2CO3, both the assertion and reason are true. - Furthermore, the reason correctly explains why the assertion is true. 5. **Final Answer**: - Both the assertion (A) and the reason (R) are true, and the reason is the correct explanation of the assertion.
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Knowledge Check

  • Phenols does not react with

    A
    sodium bicarbonate
    B
    sodium hydroxide
    C
    potassium hydroxide
    D
    ferric chloride
  • Phenol is more acidic than

    A
    B
    C
    `C_(2)H_(2)`
    D
    Both (a) and (c)
  • Phenol is more acidic than :

    A
    `C_(2)H_(5)OH`
    B
    `CH_(3)COOH`
    C
    D
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