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0.302 g of organic compound gave 0.268 g...

0.302 g of organic compound gave 0.268 g of silver bromide . The percentage of bromine in the sample is

A

20

B

50

C

37.75

D

75

Text Solution

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The correct Answer is:
To find the percentage of bromine in the organic compound using the data provided, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Given Data:** - Weight of organic compound (W_organic) = 0.302 g - Weight of silver bromide (W_AgBr) = 0.268 g - Atomic weight of bromine (Br) = 80 g/mol - Atomic weight of silver (Ag) = 108 g/mol 2. **Use the Formula for Percentage of Bromine:** The formula to calculate the percentage of halogen (in this case, bromine) using the Carrie's method is: \[ \text{Percentage of Bromine} = \left( \frac{\text{Atomic weight of Br}}{\text{Atomic weight of Br} + \text{Atomic weight of Ag}} \right) \times \left( \frac{\text{Weight of AgBr}}{\text{Weight of organic compound}} \right) \times 100 \] 3. **Substitute the Values into the Formula:** - Atomic weight of Br = 80 g/mol - Atomic weight of Ag = 108 g/mol - Substitute the values into the formula: \[ \text{Percentage of Bromine} = \left( \frac{80}{80 + 108} \right) \times \left( \frac{0.268}{0.302} \right) \times 100 \] 4. **Calculate the Denominator:** \[ 80 + 108 = 188 \] 5. **Calculate the Fraction:** \[ \frac{80}{188} \approx 0.4255 \] \[ \frac{0.268}{0.302} \approx 0.8861 \] 6. **Combine the Results:** Now, multiply the two fractions: \[ 0.4255 \times 0.8861 \approx 0.3775 \] 7. **Convert to Percentage:** \[ 0.3775 \times 100 \approx 37.75\% \] ### Final Answer: The percentage of bromine in the organic compound is **37.75%**. ---
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