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Which of the following compounds can for...

Which of the following compounds can form a Zwitter ion ?

A

Benzoic acid

B

Acetanilide

C

Aniline

D

Glycine

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds can form a zwitterion, we need to understand the structure and characteristics of zwitterions. ### Step-by-Step Solution: 1. **Definition of Zwitterion**: A zwitterion is a molecule that has both positive and negative charges, but is overall neutral. Zwitterions are commonly found in amino acids, which contain both an amino group (-NH2) and a carboxylic acid group (-COOH). 2. **Identify the Structure of Amino Acids**: The general structure of an alpha amino acid can be represented as: \[ \text{NH}_2\text{CHRCOOH} \] Here, R represents the side chain which can vary among different amino acids. 3. **Behavior in Different pH Conditions**: - **At pH < 7 (Acidic Medium)**: The carboxylic acid group is predominantly in its protonated form (-COOH), and the amino group accepts a proton to become -NH3^+. This results in a structure where there is a positive charge on the amino group and a neutral charge on the carboxylic group. - **At pH = 7 (Neutral Medium)**: The carboxylic acid group loses a proton and becomes a carboxylate ion (-COO^-), while the amino group remains protonated (-NH3^+). This results in a zwitterion with both a positive and a negative charge. - **At pH > 7 (Basic Medium)**: The carboxylic group remains in its deprotonated form (-COO^-), and the amino group is in its neutral form (-NH2). Here, the zwitterion form is not present. 4. **Identify the Given Compounds**: Among the options provided, we need to look for a compound that contains both an amino group and a carboxylic acid group. This is essential for zwitterion formation. 5. **Conclusion**: The only compound that fits this description is glycine (option D), which is the simplest amino acid. Its structure at neutral pH (pH = 7) can be represented as: \[ \text{NH}_3^+\text{CH}_2\text{COO}^- \] This confirms that glycine can form a zwitterion. ### Final Answer: The compound that can form a zwitterion is **option D: Glycine**.

To determine which of the given compounds can form a zwitterion, we need to understand the structure and characteristics of zwitterions. ### Step-by-Step Solution: 1. **Definition of Zwitterion**: A zwitterion is a molecule that has both positive and negative charges, but is overall neutral. Zwitterions are commonly found in amino acids, which contain both an amino group (-NH2) and a carboxylic acid group (-COOH). 2. **Identify the Structure of Amino Acids**: The general structure of an alpha amino acid can be represented as: \[ ...
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