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At 490^(@)C, the equilibrium constant fo...

At `490^(@)C,` the equilibrium constant for the stnthesis of HI is 50, the value of K for the dissocisation of HI will be

A

`20.0`

B

`2.0`

C

`0.2`

D

0.02`

Text Solution

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The correct Answer is:
To solve the problem, we need to find the equilibrium constant for the dissociation of HI given the equilibrium constant for the synthesis of HI. ### Step-by-Step Solution: 1. **Identify the Reaction for Synthesis of HI:** The synthesis of hydrogen iodide (HI) can be represented by the following balanced equation: \[ H_2(g) + I_2(g) \rightleftharpoons 2 HI(g) \] The equilibrium constant (K) for this reaction at \(490^\circ C\) is given as 50. 2. **Write the Expression for the Equilibrium Constant:** The equilibrium constant expression for the synthesis reaction is: \[ K_c = \frac{[HI]^2}{[H_2][I_2]} \] Given that \(K_c = 50\). 3. **Reverse the Reaction for Dissociation of HI:** The dissociation of HI can be represented by the reverse reaction: \[ 2 HI(g) \rightleftharpoons H_2(g) + I_2(g) \] 4. **Determine the Equilibrium Constant for the Reversed Reaction:** When a reaction is reversed, the equilibrium constant for the reverse reaction (let's call it \(K'\)) is the reciprocal of the equilibrium constant for the forward reaction: \[ K' = \frac{1}{K_c} \] Therefore, substituting the value of \(K_c\): \[ K' = \frac{1}{50} \] 5. **Calculate the Value of \(K'\):** Performing the calculation: \[ K' = 0.02 \] 6. **Conclusion:** The value of the equilibrium constant for the dissociation of HI at \(490^\circ C\) is: \[ K' = 0.02 \] ### Final Answer: The value of \(K\) for the dissociation of HI is **0.02**.

To solve the problem, we need to find the equilibrium constant for the dissociation of HI given the equilibrium constant for the synthesis of HI. ### Step-by-Step Solution: 1. **Identify the Reaction for Synthesis of HI:** The synthesis of hydrogen iodide (HI) can be represented by the following balanced equation: \[ H_2(g) + I_2(g) \rightleftharpoons 2 HI(g) ...
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