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Which of the following has highest molar...

Which of the following has highest molar conductivity

A

Diamminedichloroplatinum (II)

B

Tetraaminedichlorocobalt (III) chloride

C

Potassium hexacyanoferrate (II)

D

Hexaaquochromium (III) bromide

Text Solution

Verified by Experts

The correct Answer is:
C

As the number of ionsif complex compounds when dissolved in water increases, molar conductivity also increases.
1 mole of `[Pt(NH_(3))_(2)Cl_(2)]` gives one mole of ions.
1 mole of `[Co(NH_(3))_(4)Cl_(2)]Cl` gives two mole of ions
1 mole of `K_(4)[Fe(CN)_(6)]` gives five moles of ions
1mole of `[Fe(CO)_(5)]` gives zero moles of ions `[` because it is a neutral molecule ]
Hence, `K_(4)[Fe(CN)_(6)]` has the highest molar conductivity
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