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Which of the following pairs represents ...

Which of the following pairs represents linkage isomers

A

`[Cu(NH_(3))_(4)][PtCl_(4)]` and `[Pt(NH_(3))_(4)][CuCl_(4)]`

B

`[Pd(P Ph_(3))_(2)(NCS)_(2)` and `[Pd(P Ph_(3))_(2)(SCN)_(2)]`

C

`[Co(NH_(3))_(5)NO_(3)]SO_(4)` and `[Co(NH_(3))_(5)SO_(4)]NO_(3)`

D

`[PtCl_(2)(NH_(3))_(4)]Br_(2)` and `[Pt Br_(2)(NH_(3))_(4)]Cl_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B
`SCN^(-)` ion can coordinate through the sulphur or nitrogen atom. Such possibilities give rise to linkage isomerism in coordination compounds.
`M larr SCN` Thiocyanato or thiocyanato -S
`M larr NCS` Isothiocyanato or thiocyanato-N
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ERRORLESS -COORDINATION CHEMISTRY-ORDINARY THINKING Objective Questions (Isomerism and Magnetic properties)
  1. The magnetic moment (spin only) of [NiCl(4)]^(2-) is

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  2. Which of the following has an optical isomer?

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  3. Which of the following pairs represents linkage isomers

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  4. The magnetic moment of salt containing Zn^(2+) ion is :

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  5. The ion of least magnetic moment among the following is

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  6. The optically active co-ordination complex ion among the following is

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  7. The complesx [CoF(6)]^(4-) is

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  8. Which is high spin complex

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  9. For the given complex [CoCl(2)(en)(NH(3))(2)]^(+), the number of geome...

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  10. Which of the following can participate in linkage isomerism

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  11. The magnetic moment of a transition metal is sqrt(15) B.M . Find out ...

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  12. The spin only magnetic moment of Mn^(4+) ion is nearly

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  13. Amongst [NiCl(4)]^(2-), [Ni(H(2)O)(6)]^(2+), [Ni(PPh(3))(2)Cl(2)], [Ni...

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  14. The spin-only magnetic moment of [CrF(6)]^(4) ( atomic number of Cr is...

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  15. What is the magnetic moment of K(3)[FeF(6)] ?

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  16. How many unpaired electrons are present in the central metal ion of [C...

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  17. The reaction [Fe(CN)(6)]^(3-) rarr [FeF(6)]^(3-) takes place with

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  18. Which of the following can exhibit geometrical isomerism

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  19. Which of the following is diamagnetic in nature

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  20. Coordination isomerism is caused by the interchange of ligands between...

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