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Which of the following pairs represents ...

Which of the following pairs represents linkage isomers

A

`[Cu(NH_(3))_(4)][PtCl_(4)]` and `[Pt(NH_(3))_(4)][CuCl_(4)]`

B

`[Pd(P Ph_(3))_(2)(NCS)_(2)` and `[Pd(P Ph_(3))_(2)(SCN)_(2)]`

C

`[Co(NH_(3))_(5)NO_(3)]SO_(4)` and `[Co(NH_(3))_(5)SO_(4)]NO_(3)`

D

`[PtCl_(2)(NH_(3))_(4)]Br_(2)` and `[Pt Br_(2)(NH_(3))_(4)]Cl_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B
`SCN^(-)` ion can coordinate through the sulphur or nitrogen atom. Such possibilities give rise to linkage isomerism in coordination compounds.
`M larr SCN` Thiocyanato or thiocyanato -S
`M larr NCS` Isothiocyanato or thiocyanato-N
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Knowledge Check

  • Which of the folloing pairs represents linkage isomers ?

    A
    `[Pd(P Ph_(3))_(2) (NCS)_(2)] and [Pd(P Ph_(3))_(2)(SCN)_(2)]`
    B
    `[Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5)SO_(4)]NO_(3)`
    C
    `[PtCl_(2)(NH_(3))_(4)Br_(2) and [PtBr_(2) (NH_(3))_(4)]Cl_(2)`
    D
    `[Cu(NH_(3))_(4)][PtCl_(4)] and [Pt(NH_(3))_(4)][CuCl_(4)]`

  • Which of the following pairs represents linakage isomers ?

    A
    `[Cu(NH_(3))_(4)][PtCl_(4)] and [Pt(NH_(3))_(4)][CuCl_(4)]`
    B
    `[Pd("PP"h_(3))_(2) (NCS)_(2) ] and [Pd("PP"h_(3))_(2) (SCN)_(2)]`
    C
    `[Co(NH_(3))_(5)NO_(3) SO_(4) and [Co(NH_(3))_(5)SO_(4)]NO_(3)`
    D
    `[Pt(Cl_(2)(NH_(3))_(4)]Br_(2) and [PtBr_(2)(NH_(3))_(4)]Cl_(2)`

  • Which of the following pairs represents isobars?

    A
    `._(19)K^(40)` and `._(11)Na^(23)`
    B
    `._(2)He^(3)` and `._(2)He^(4)`
    C
    `._(12)Mg^(24)` and `._(12)Mg^(25)`
    D
    `._(19)K^(40)` and `._(20)Ca^(40)`

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