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Reaction of benzene with Me3COCl in the ...

Reaction of benzene with `Me_3COCl` in the presence of anhydrous `AlCl_3` gives

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To solve the question regarding the reaction of benzene with `Me3COCl` in the presence of anhydrous `AlCl3`, we can follow these steps: ### Step 1: Understand the Reactants We have benzene (C6H6) and `Me3COCl` (tert-butyl chloride). The `Me3CO` part is a tert-butyl group, which is a tertiary alkyl group. ### Step 2: Role of Anhydrous AlCl3 Anhydrous aluminum chloride (AlCl3) acts as a Lewis acid. It interacts with `Me3COCl` to form a more reactive species. The AlCl3 coordinates with the chlorine atom in `Me3COCl`, facilitating the generation of a carbocation. ### Step 3: Formation of the Carbocation When `Me3COCl` reacts with AlCl3, the chlorine atom leaves, and a tert-butyl cation (`Me3C+`) is formed. The reaction can be summarized as follows: - `Me3COCl + AlCl3 → Me3C+ + AlCl4-` ### Step 4: Electrophilic Aromatic Substitution The tert-butyl cation (`Me3C+`) is a strong electrophile. It will react with benzene through an electrophilic aromatic substitution mechanism. The benzene ring donates one of its π electrons to the carbocation, forming a sigma complex (also known as an arenium ion). ### Step 5: Deprotonation The sigma complex formed will lose a proton (H+) to restore aromaticity. This step regenerates the aromatic system of benzene and leads to the final product. ### Step 6: Final Product The final product of the reaction is tert-butylbenzene. The structure can be represented as: - C6H5-C(CH3)3 ### Conclusion The reaction of benzene with `Me3COCl` in the presence of anhydrous `AlCl3` gives tert-butylbenzene. ---

To solve the question regarding the reaction of benzene with `Me3COCl` in the presence of anhydrous `AlCl3`, we can follow these steps: ### Step 1: Understand the Reactants We have benzene (C6H6) and `Me3COCl` (tert-butyl chloride). The `Me3CO` part is a tert-butyl group, which is a tertiary alkyl group. ### Step 2: Role of Anhydrous AlCl3 Anhydrous aluminum chloride (AlCl3) acts as a Lewis acid. It interacts with `Me3COCl` to form a more reactive species. The AlCl3 coordinates with the chlorine atom in `Me3COCl`, facilitating the generation of a carbocation. ...
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