Home
Class 12
CHEMISTRY
How would you account for the following:...

How would you account for the following:
The electron gain enthalpy with negative sign for fluorine is less than that for chlorine, still fluorine is a stronger oxidising agent than chlorine.

Text Solution

Verified by Experts

Fluorine is upper in the Group 17 than Cl. Therefore F is a more electronegative and hence stronger oxidising agent than chlorine.
But the electron gain enthalpy with negative sign for fluorine is less than that for chlorine. This is because fluorine atom being smaller cannot accommodate more electrons easily due to inter-electronic repulsions. Hence less energy is released with `F_2`
Promotional Banner

Topper's Solved these Questions

  • THE P-BLOCK ELEMENTS

    U-LIKE SERIES|Exercise LONG ANSWER QUESTION-II|68 Videos
  • THE P-BLOCK ELEMENTS

    U-LIKE SERIES|Exercise SELF ASSESSMENT TEST ( SECTION A)|7 Videos
  • THE P-BLOCK ELEMENTS

    U-LIKE SERIES|Exercise SHORT ANSWER QUESTIONS|87 Videos
  • THE D-AND F-BLOCK ELEMENTS

    U-LIKE SERIES|Exercise SELF ASSESSMENT TEST (SECTION A ) MULTIPLE CHOICE QUESTIONS (CHOOSE THE CORRECT OPTION)|7 Videos

Similar Questions

Explore conceptually related problems

Explain the following : (a) The electron gain enthalpy with negative sign for fluorine is less than for chlorine, still fluorine is a stronger oxidising agent than chlorine. (b) XeF_(2) is linear molecule without a bend. (c) NCl_(3) is an endothermic compound while NF_(3) is an exothermic one.

Although Delta_(eg)H of luorine is less negative than that of chlorine, but fluorine is a stronger oxidising agent than chlorine. Why?

In aqueous solution , chlorine is a stronger oxidising agent than fluorine.

U-LIKE SERIES-THE P-BLOCK ELEMENTS -LONG ANSWER QUESTION-I
  1. How would you account for the following: NCI3 is an endothermic co...

    Text Solution

    |

  2. How would you account for the following: XeF2 is a linear molecule ...

    Text Solution

    |

  3. How would you account for the following: The electron gain enthalpy...

    Text Solution

    |

  4. Write balanced chemical equations for the following reactions : Ther...

    Text Solution

    |

  5. Write balanced chemical equations for the following reactions : Reac...

    Text Solution

    |

  6. Write balanced chemical equations for the following reactions : When...

    Text Solution

    |

  7. Account for the following: NH3 is a stronger base than PH3.

    Text Solution

    |

  8. Account for the following: Sulphur has a greater tendency for cate...

    Text Solution

    |

  9. Account for the following: Bond dissociation energy of F2 is less ...

    Text Solution

    |

  10. Explain the following situations : In the structure of HNO3 molecul...

    Text Solution

    |

  11. Explain the following situations : SF4 is easily hydrolysed whereas...

    Text Solution

    |

  12. Explain the following situations : XeF2 has a straight linear stru...

    Text Solution

    |

  13. Explain the following observations giving appropriate reasons : Oz...

    Text Solution

    |

  14. Explain the following observations giving appropriate reasons : Th...

    Text Solution

    |

  15. Explain the following observations giving appropriate reasons : Bl...

    Text Solution

    |

  16. Account for the following observations: among the halogens F2 is th...

    Text Solution

    |

  17. Account for the following observations: fluorine exhibits only -1 o...

    Text Solution

    |

  18. Account for the following observations: acidity of oxo acid of chlo...

    Text Solution

    |

  19. Account for the following: Neon is not known to form compounds.

    Text Solution

    |

  20. Account for the following: Although the electron gain enthalpy of f...

    Text Solution

    |