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Answer any five of the following questio...

Answer any five of the following questions.
a) Given reason: (i) Hydrogen bonding in `H_2 O` but not in `H_2 S`
(ii) Conc. `H_2 SO_4` is a good dehydrating agent

Text Solution

Verified by Experts

(a) (i) Since oxygen is more electronegative and has small size.
(ii) Due to strong affinity for water/it removes elements of water in the form of `H_2O`
(b)
Detailed Answer: 
(a) (i) (A) In water, the oxygen atom is highly electronegative and can polarize (partially) the hydrogen atoms, thus hydrogen-hydrogen bonds between the `H_2O` molecules results in the creation of a stable intermolecular network and the very high boiling point of water and alcohols. In `H_2S` those bonds don.t exist, because sulphur is much less electronegative.
(B) Another reason may be that O uses `sp^(3)` orbitals, and thus alone may be able to form stable hydrogen bonds. By comparison S use p orbitals, which may not be able to form stable hydrogen bonds. (Any other correct justification)
(ii) Because it has a strong affinity for water and thus it absorbs water quickly.
(b) In sulphurous acid, one atom of sulphur is bonded to two hydroxyl groups and one oxygen atom forms `a pi` bond with the sulphur atom.
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Similar Questions

Explore conceptually related problems

Show that Conc. H_(2)SO_(4) is a dehydrating agent.

(a) Give reason: (i) Hydrogen bonding in H_(2)O but not in H_(2)S . (ii) Conc. H_(2)SO_(4) is a good dehydrating agent. (b) Give the structure of sulphurous acid ( H_(2)SO_(3) ).

Knowledge Check

  • In which of the following reactions, H_2O_2 acts as reducing agent?

    A
    `H_2O_2 + SO_2 rarr H_2SO_4`
    B
    `2KI + H_2O_2 rarr 2KOH + I_2`
    C
    `PbS + 4H_2O_2 rarr PbSO_4 + 4H_2O`
    D
    `Ag_2O + H_2O_2 rarr 2Ag + H_2O + O_2`.
  • Maximum number of hydrogen bonds in H_2O are

    A
    1
    B
    2
    C
    3
    D
    4
  • In which of the following reaction H_(2)O_(2) is acting as a reducing agent

    A
    `SO_(2)+H_(2)O_(2)rarrH_(2)SO_(4)`
    B
    `2KI+H_(2)O_(2)rarr2KOH+I_(2)`
    C
    `PbS+4H_(2)O_(2)rarrPbSO_(4)+4H_(2)O`
    D
    `Ag_(2)O+H_(2)O_(2)rarr2Ag+H_(2)O+O_(2)`
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