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The limiting molar conductivities ^^ ^(@...

The limiting molar conductivities `^^ ^(@)` for NaCl , KBr , and KCl are 126 , 152 and 150 `S cm^(2) mol^(-1)` respectively. The `^^ ^(@)` for NaBr_________.

A

278 S `cm^(2)mol^(-1)`

B

176 S `cm^(2)mol^(-1)`

C

128S `cm^(2)mol^(-1)`

D

302 S `cm^(2)mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
C

`(126s" "cm^(2))wedge_(NaCl)^(o)=wedge_(Na^(+))^(o)+wedge_(Cl^(-))^(o)` . . .(i)
`(152s" "cm^(2))wedge_(KBr)^(o)=wedge_(K^(+))^(o)+wedge_(Br^(-))^(o)` . . . (ii)
`(150s" "cm^(2))wedge_(KCl)^(o)=wedge_(K^(+))^(o)+wedge_(Cl^(-))^(o)` . . .(iii)
by equation (i)+(ii)-(iii)
`because wedge_(NaBr)^(o)=wedge_(Na^(+))^(o)+wedge_(Br^(-))^(o)` ltBrgt `=126+152-150=128s" "cm^(2)mol^(-1)`.
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