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Assertion : C(3)O(2) is non-polar molecu...

Assertion : `C_(3)O_(2)` is non-polar molecule.
Reason : Terminal `pi-bonds of the molecule are lying in different planes.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true and the reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided, we will go through the following steps: ### Step 1: Understanding the Assertion The assertion states that \( C_3O_2 \) is a non-polar molecule. To evaluate this, we need to consider the molecular geometry and the distribution of charges within the molecule. ### Step 2: Drawing the Structure of \( C_3O_2 \) The structure of \( C_3O_2 \) can be represented as follows: - The molecule consists of three carbon atoms connected by double bonds, with the terminal carbon atoms bonded to oxygen atoms through double bonds. - The structure can be depicted as: \[ C=C=C=O \] where the terminal carbon (C) is double-bonded to oxygen (O). ### Step 3: Analyzing Electronegativity In \( C_3O_2 \), oxygen is more electronegative than carbon. This means that the oxygen atoms will attract the shared electrons in the double bonds more strongly than the carbon atoms. As a result, there will be a partial negative charge on the oxygen atoms and a partial positive charge on the carbon atoms, leading to a dipole moment. ### Step 4: Conclusion on the Assertion Since there is an unequal distribution of charge due to the electronegativity difference, \( C_3O_2 \) is a polar molecule. Therefore, the assertion that \( C_3O_2 \) is non-polar is **false**. ### Step 5: Understanding the Reason The reason states that the terminal pi-bonds of the molecule are lying in different planes. To evaluate this, we need to analyze the geometry of the molecule. ### Step 6: Analyzing the Molecular Geometry In the structure of \( C_3O_2 \): - The terminal pi-bonds (C=O) are indeed oriented in different planes due to the arrangement of the p-orbitals involved in bonding. - The p-orbitals of the carbon atoms and oxygen atoms can be oriented such that the pi-bonds are not in the same plane. ### Step 7: Conclusion on the Reason The reason provided is **true** because the terminal pi-bonds are indeed lying in different planes. ### Final Conclusion - The assertion is **false**: \( C_3O_2 \) is a polar molecule. - The reason is **true**: The terminal pi-bonds are lying in different planes. - Therefore, the reason does not provide a correct explanation for the assertion.
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