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O(2)^(2-) will have ....

`O_(2)^(2-)` will have .

A

bond order equal to `H_(2)` and diamagnetic

B

bond order equal to `H_(2)` but diamagnetic

C

bond order equal to `N_(2)` and diamagnetic

D

bond order higher than `O_(2)`

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The correct Answer is:
To determine the bond order of the \( O_2^{2-} \) ion, we will follow these steps: ### Step 1: Write the Electronic Configuration The electronic configuration of the \( O_2 \) molecule is: \[ \sigma_{1s}^2 \, \sigma_{1s}^*^2 \, \sigma_{2s}^2 \, \sigma_{2s}^*^2 \, \sigma_{2p_x}^2 \, \pi_{2p_y}^2 \, \pi_{2p_z}^2 \, \pi_{2p_y}^*^0 \, \pi_{2p_z}^*^0 \] For \( O_2^{2-} \), we add two additional electrons to the \( O_2 \) configuration, filling the antibonding orbitals: \[ \sigma_{1s}^2 \, \sigma_{1s}^*^2 \, \sigma_{2s}^2 \, \sigma_{2s}^*^2 \, \sigma_{2p_x}^2 \, \pi_{2p_y}^2 \, \pi_{2p_z}^2 \, \pi_{2p_y}^*^2 \, \pi_{2p_z}^*^2 \] ### Step 2: Count Bonding and Antibonding Electrons - **Bonding Electrons (NB)**: - \( \sigma_{1s}^2 \) = 2 - \( \sigma_{2s}^2 \) = 2 - \( \sigma_{2p_x}^2 \) = 2 - \( \pi_{2p_y}^2 \) = 2 - \( \pi_{2p_z}^2 \) = 2 - Total = \( 2 + 2 + 2 + 2 + 2 = 10 \) - **Antibonding Electrons (NA)**: - \( \sigma_{1s}^*^2 \) = 2 - \( \sigma_{2s}^*^2 \) = 2 - \( \pi_{2p_y}^*^2 \) = 2 - \( \pi_{2p_z}^*^2 \) = 2 - Total = \( 2 + 2 + 2 + 2 = 8 \) ### Step 3: Calculate Bond Order The bond order is calculated using the formula: \[ \text{Bond Order} = \frac{1}{2} (NB - NA) \] Substituting the values: \[ \text{Bond Order} = \frac{1}{2} (10 - 8) = \frac{1}{2} \times 2 = 1 \] ### Step 4: Determine Magnetic Properties Since all molecular orbitals are completely filled, \( O_2^{2-} \) is diamagnetic. ### Final Answer The bond order of \( O_2^{2-} \) is 1, and it is diamagnetic. ---

To determine the bond order of the \( O_2^{2-} \) ion, we will follow these steps: ### Step 1: Write the Electronic Configuration The electronic configuration of the \( O_2 \) molecule is: \[ \sigma_{1s}^2 \, \sigma_{1s}^*^2 \, \sigma_{2s}^2 \, \sigma_{2s}^*^2 \, \sigma_{2p_x}^2 \, \pi_{2p_y}^2 \, \pi_{2p_z}^2 \, \pi_{2p_y}^*^0 \, \pi_{2p_z}^*^0 \] For \( O_2^{2-} \), we add two additional electrons to the \( O_2 \) configuration, filling the antibonding orbitals: ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises Linked Comprehension
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  4. Consider the following molecules . A:Anti -pyridine -2-carboxaldoxime...

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  5. Valence-bond theory is one of the two quantum mechanical approaches th...

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  6. Valence-bond theory is one of the two quantum mechanical approaches th...

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  7. Valence-bond theory is one of the two quantum mechanical approaches th...

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  8. Valence-bond theory is one of the two quantum mechanical approaches th...

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  9. Which of the following statements is correct about O(2),O(2)^(Θ),O(2)^...

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  10. O(2)^(2-) will have .

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  11. According to the moleular orbital theory, all atomic orbitals combine ...

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  12. According to the moleular orbital theory, all atomic orbitals combine ...

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  13. Most of the polyatomic molecules except a few such as CO(2) and CS(2) ...

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  14. Which of the following have highest bond angle ? .

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  15. Which of the following hybridisation may have more than one type of bo...

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  16. Which one of the following statements is correct .

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  17. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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  18. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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  19. Which one of the following has maximum number of nodal planes ? .

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  20. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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