Home
Class 11
CHEMISTRY
O(2)^(2-) will have ....

`O_(2)^(2-)` will have .

A

bond order equal to `H_(2)` and diamagnetic

B

bond order equal to `H_(2)` but diamagnetic

C

bond order equal to `N_(2)` and diamagnetic

D

bond order higher than `O_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the bond order of the \( O_2^{2-} \) ion, we will follow these steps: ### Step 1: Write the Electronic Configuration The electronic configuration of the \( O_2 \) molecule is: \[ \sigma_{1s}^2 \, \sigma_{1s}^*^2 \, \sigma_{2s}^2 \, \sigma_{2s}^*^2 \, \sigma_{2p_x}^2 \, \pi_{2p_y}^2 \, \pi_{2p_z}^2 \, \pi_{2p_y}^*^0 \, \pi_{2p_z}^*^0 \] For \( O_2^{2-} \), we add two additional electrons to the \( O_2 \) configuration, filling the antibonding orbitals: \[ \sigma_{1s}^2 \, \sigma_{1s}^*^2 \, \sigma_{2s}^2 \, \sigma_{2s}^*^2 \, \sigma_{2p_x}^2 \, \pi_{2p_y}^2 \, \pi_{2p_z}^2 \, \pi_{2p_y}^*^2 \, \pi_{2p_z}^*^2 \] ### Step 2: Count Bonding and Antibonding Electrons - **Bonding Electrons (NB)**: - \( \sigma_{1s}^2 \) = 2 - \( \sigma_{2s}^2 \) = 2 - \( \sigma_{2p_x}^2 \) = 2 - \( \pi_{2p_y}^2 \) = 2 - \( \pi_{2p_z}^2 \) = 2 - Total = \( 2 + 2 + 2 + 2 + 2 = 10 \) - **Antibonding Electrons (NA)**: - \( \sigma_{1s}^*^2 \) = 2 - \( \sigma_{2s}^*^2 \) = 2 - \( \pi_{2p_y}^*^2 \) = 2 - \( \pi_{2p_z}^*^2 \) = 2 - Total = \( 2 + 2 + 2 + 2 = 8 \) ### Step 3: Calculate Bond Order The bond order is calculated using the formula: \[ \text{Bond Order} = \frac{1}{2} (NB - NA) \] Substituting the values: \[ \text{Bond Order} = \frac{1}{2} (10 - 8) = \frac{1}{2} \times 2 = 1 \] ### Step 4: Determine Magnetic Properties Since all molecular orbitals are completely filled, \( O_2^{2-} \) is diamagnetic. ### Final Answer The bond order of \( O_2^{2-} \) is 1, and it is diamagnetic. ---

To determine the bond order of the \( O_2^{2-} \) ion, we will follow these steps: ### Step 1: Write the Electronic Configuration The electronic configuration of the \( O_2 \) molecule is: \[ \sigma_{1s}^2 \, \sigma_{1s}^*^2 \, \sigma_{2s}^2 \, \sigma_{2s}^*^2 \, \sigma_{2p_x}^2 \, \pi_{2p_y}^2 \, \pi_{2p_z}^2 \, \pi_{2p_y}^*^0 \, \pi_{2p_z}^*^0 \] For \( O_2^{2-} \), we add two additional electrons to the \( O_2 \) configuration, filling the antibonding orbitals: ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct(Chemical Bonding )|7 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct (Dipole Moment)|3 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 2 .2 Objective|34 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Concept Applicationexercise(4.3)|19 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective type|1 Videos

Similar Questions

Explore conceptually related problems

S_(2)O_(8)^(2-) have

Statement-1 : O_(2)^(-) and O_(2)^(+) are paramagnetic . and Statement-2 : Bond order of O_(2)^(+) and O_(2)^(-) is same .

Knowledge Check

  • Assertion : F_(2)and O_(2)^(2-) have bond order 1 while N_(2),CO and NO^(+) have bond order 3. Reason : Higher the bond order, higher is the stability of the molecule.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason in not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
  • Assertion : In gaseous phase, H_(2)O and H_(2)O_(2) both have bent structures. Reason Bond angle of both H_(2)O and H_(2)O_(2) is 104.5^(@) .

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
  • Similar Questions

    Explore conceptually related problems

    Which of the following statements is correct about O_(2),O_(2)^(Θ),O_(2)^(2-) species ? .

    Assertion O_(2) and N_(2)^(2-) have same number of electrons and same molecular orbital configuration Reasoning O_(2) and N_(2)^(2-) have the same bond order .

    Assertion: When two gaseous OF molecules are allowed to cool, then they undergo dimerisation through O-atom. Reason: Dimerr form of OF molecule (i.e, O_(2)F_(2) ) is having one peroxy linkage in its structure.

    Assertion : When two gaseous OF molecules are allowed to cool, than they undergoes dimerisation through O-atom. Reason : Dimer form of OF molecule (i.e., O_(2)F_(2) ) is having one peroxy linkage in its structure.

    Which of the following facts given is not correct? (I) Bond length order, H_(2)^(-)-H_(2)^(+)gtH_(2) (II) O_(2)^(+), NO, N_(2)^(-) have same bond order of 2(1)/(2) (II) Bond order can assume any value including zero upto four (IV) NO_(3)^(-) and BO_(3)^(-) have same order for X-O bond (where X is central atom)

    The bond length the species O_(2), O_(2)^(+) and O_(2)^(-) are in the order of