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When phosphine is bubbled through a solu...

When phosphine is bubbled through a solution of silver nitrate ___ is precipitated.

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To solve the question, we need to analyze the reaction that occurs when phosphine (PH₃) is bubbled through a solution of silver nitrate (AgNO₃). Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Reactants - **Phosphine (PH₃)**: This is the compound that will react with silver nitrate. - **Silver Nitrate (AgNO₃)**: This is the solution through which phosphine is bubbled. **Hint**: Recognize the chemical formulas of the reactants involved in the reaction. ### Step 2: Understand the Reaction When phosphine is bubbled through silver nitrate solution, it can dissociate into its ions: - Phosphine (PH₃) can be represented as producing phosphide ions (P³⁻) and hydrogen ions (H⁺). - Silver nitrate (AgNO₃) dissociates into silver ions (Ag⁺) and nitrate ions (NO₃⁻). **Hint**: Consider how each compound breaks down into its constituent ions in solution. ### Step 3: Write the Ionic Equation The ions that are formed in the solution are: - From PH₃: P³⁻ and H⁺ - From AgNO₃: Ag⁺ and NO₃⁻ The relevant reaction can be written as: \[ \text{3Ag}^+ + \text{P}^{3-} \rightarrow \text{Ag}_3\text{P} \] **Hint**: Focus on how the cations and anions interact to form a precipitate. ### Step 4: Identify the Precipitate The combination of silver ions (Ag⁺) and phosphide ions (P³⁻) leads to the formation of silver phosphide (Ag₃P), which is a solid precipitate. The other product formed in this reaction is nitric acid (HNO₃) from the remaining ions (H⁺ and NO₃⁻). **Hint**: Remember that a precipitate is a solid that forms from a solution during a chemical reaction. ### Step 5: Conclusion When phosphine is bubbled through a solution of silver nitrate, the precipitate formed is silver phosphide (Ag₃P). **Final Answer**: Silver phosphide (Ag₃P) is precipitated. ---
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Knowledge Check

  • When a copper wire is dipped into silver nitrate solution, silver is precipitated because

    A
    both silver and copper have positive reduction potentials
    B
    reduction potential of silver is higher than that of copper
    C
    reduction potential of copper is higher than that of silver
    D
    both silver and copper have negative reduction potentials.
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