Home
Class 12
CHEMISTRY
Oxygen exists as a gas, while sulphur ex...

Oxygen exists as a gas, while sulphur exists as a solid Why ?

Text Solution

Verified by Experts

Oxygen , due to its small size is capable of forming `pi` bond and hence exist as `O=O` i.e. `O_(2)` molecule. `O_(2)` molecules are hend together by weak van der Waals forces of attaction, hence oxygen exists as a gas. On the other hand, sulphur due to its large size, is not capable of forming `pi-bonds`, rather each S-atom is `sp^(3)` hybridised and sulphur exists as `S_(8)` molecules. Due to high molecular mass of `S_(8)`, van der Waals forces of attaction between `S_(8)` molecules is large and sulphur exists as a solid.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • P-BLOCK GROUP 16 ELEMENTS - THE OXYGEN FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 3.1Objective (Choose The Correct Option)|11 Videos
  • P-BLOCK GROUP 16 ELEMENTS - THE OXYGEN FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Linked Comprehension)|23 Videos
  • P-BLOCK GROUP 16 ELEMENTS - THE OXYGEN FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Example|5 Videos
  • P-BLOCK GROUP 15 ELEMENTS - THE NITROGEN FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Subjective)|28 Videos
  • P-BLOCK GROUP 17 ELEMENTS - THE HALOGEN FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise True/False (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

Statement-1 : At room temperature oxygen exists as a diatomic gas, where as sulphur exists as solid. Statement-2 : The catenated -O-O-O- chains are less stable as compared to O=O molecule.

Nitrogen is a gas, while other members of group 15 are solids. Why ?

(A) Complete the following chemical equations : (i) Cu+HNO_(3) (dilute) to (ii) XeF_(4)+O_(2)F_(2)to (B) Explain the following observations: (i) Phosphorous has greater tendency for catenation than nitrogen. (ii) Oxygen is a gas but sulphur is a solid. (iii) The halogens are coloured. Why ?

The solid PCl_5 exists as

Why is dioxygen a gas but sulphur a solid?

State true or false Oxygen is a gas but sulphur a solid.

Why boron halides do not exists as a dimer. While AlCl_(3) exists as Al_(2)Cl_(6) ?

Why do some substance exist as solids?

Why carbon exists as the hardest crystalline solid, though it is a non metal?

Nitrogen exists as diatomic molecule and phosphorus as P_(4) . Why ?