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The oxide that gives H(2)O(2) on treatme...

The oxide that gives `H_(2)O_(2)` on treatment with a dilute sulfuric acid is

A

`PbO_2`

B

`Na_2 O_2`

C

`MnO_2`

D

`TiO_2`

Text Solution

Verified by Experts

The correct Answer is:
B

Only true peroxides which have `O-O-bond` give hydrogen perxide with dilute acids.
`Na_(2) O_(2) + H_(2) SO_(4) rarr Na_(2) SO_(4) + H_(2) O_(2)`
Note :
(i) But peroxide with conc. Acids leberates `H_(2) O_(2)` and `O_(2)`, e.g.
`BaO_(2) + H_(2) SO_(4) (dil.) rarr BaSO_(4) + H_(2) O_(2)`
`BaO_(2) + 2H_(2) SO_(4) (conc.) rarrr 2 BaSO_(4) + 2 H_(2) O_(2) + O_(2)`
(ii) Superoxides (e.g., `KO_(2), RbO_(2), CsO_(2))` react with water to give `H_(2) O_(2)` and `O_(2)`.
`2 KO_(2) + 2H_(2) O rarr 2 KOH + H_(2) O_(2) + O_(2)`.
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Knowledge Check

  • The oxide that give H_(2)O_(2) on treatment with dilute H_(2)SO_(4) is

    A
    `PbO_(2)`
    B
    `BaO_(2).8H_(2)O`
    C
    `MnO_(2)`
    D
    `TiO_(2)`
  • Propanal on treatment with dilute sodium hydroxide gives

    A
    `CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)CHO`
    B
    `CH_(3)CH_(2)CH(OH)CH_(2)CH_(2)CHO`
    C
    `CH_(3)CH_(2)CH(OH)CH(CH_(3))CHO`
    D
    `CH_(3)CH_(2)COOH`
  • An ore gives CO_2 on being treated with dilute hydrochloric acid. Which process should be used to convert this ore into oxide?

    A
    Calcination
    B
    Roasting
    C
    Froth floatation
    D
    Sedimentation
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