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Species having the formula XZ(4) is give...

Species having the formula `XZ_(4)` is given below `SF_(4)`, Define shape on the basis of the location of X and Z atoms.

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To determine the shape of the species SF₄ (where X = S and Z = F), we will follow these steps: ### Step 1: Identify the Central Atom The central atom in SF₄ is sulfur (S). ### Step 2: Determine the Valence Electrons Sulfur has 6 valence electrons. ### Step 3: Count the Bonding Atoms In SF₄, there are 4 fluorine (F) atoms bonded to the sulfur atom. ### Step 4: Calculate the Steric Number The steric number is calculated using the formula: \[ \text{Steric Number} = \text{Number of Bonding Pairs} + \text{Number of Lone Pairs} \] - **Bonding Pairs**: There are 4 fluorine atoms, which means there are 4 bonding pairs. - **Lone Pairs**: Sulfur has 6 valence electrons and uses 4 for bonding with fluorine. Therefore, it has \( 6 - 4 = 2 \) electrons left, which form 1 lone pair. Thus, the steric number is: \[ \text{Steric Number} = 4 \text{ (bonding pairs)} + 1 \text{ (lone pair)} = 5 \] ### Step 5: Determine Hybridization With a steric number of 5, the hybridization of sulfur is \( sp^3d \). ### Step 6: Determine the Geometry The geometry corresponding to \( sp^3d \) hybridization is trigonal bipyramidal. ### Step 7: Consider the Lone Pair Effect In a trigonal bipyramidal arrangement, the lone pair occupies one of the equatorial positions. The presence of the lone pair causes repulsion, which distorts the shape. ### Step 8: Define the Final Shape Due to the lone pair's repulsion, the shape of SF₄ is not a perfect trigonal bipyramidal but rather a see-saw shape. ### Final Answer The shape of SF₄ is a see-saw due to the presence of one lone pair on the sulfur atom, which affects the arrangement of the four fluorine atoms. ---

To determine the shape of the species SF₄ (where X = S and Z = F), we will follow these steps: ### Step 1: Identify the Central Atom The central atom in SF₄ is sulfur (S). ### Step 2: Determine the Valence Electrons Sulfur has 6 valence electrons. ...
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A species having the formula XZ_(4) is given below : XeF_(4), Identify the shape.

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Knowledge Check

  • SF_(4) has _____shape.

    A
    T-shape
    B
    Bent
    C
    Octahedral
    D
    see saw
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