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Which of the following are nucleophiles ...

Which of the following are nucleophiles ?

A

`PH_3`

B

`F^(Ө)`

C

`NH_3`

D

`H_2 O`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given options are nucleophiles, we need to understand the definition and characteristics of nucleophiles. ### Step-by-Step Solution: 1. **Define Nucleophiles**: - Nucleophiles are chemical species that are "nucleus-loving." They are characterized by having an abundance of electrons, which makes them electron-rich. - They must contain at least one lone pair of electrons. - Nucleophiles can be negatively charged or neutral. 2. **Analyze Each Option**: - **Option 1: PH3 (Phosphine)**: - Phosphorus (P) has five valence electrons. In PH3, phosphorus forms three bonds with hydrogen and retains one lone pair of electrons. - Since PH3 has a lone pair, it qualifies as a nucleophile. - **Option 2: F⁻ (Fluoride Ion)**: - The fluoride ion has three lone pairs of electrons and carries a negative charge. - Being negatively charged and having lone pairs, F⁻ is a strong nucleophile. - **Option 3: NH3 (Ammonia)**: - Nitrogen (N) has five valence electrons. In NH3, nitrogen forms three bonds with hydrogen and has one lone pair of electrons. - The presence of a lone pair means NH3 is also a nucleophile. - **Option 4: H2O (Water)**: - Oxygen (O) has six valence electrons. In H2O, oxygen forms two bonds with hydrogen and retains two lone pairs of electrons. - The two lone pairs indicate that H2O is also a nucleophile. 3. **Conclusion**: - All the options provided (PH3, F⁻, NH3, and H2O) are nucleophiles because they all contain at least one lone pair of electrons and are electron-rich species. ### Final Answer: All of the given options are nucleophiles: PH3, F⁻, NH3, and H2O.

To determine which of the given options are nucleophiles, we need to understand the definition and characteristics of nucleophiles. ### Step-by-Step Solution: 1. **Define Nucleophiles**: - Nucleophiles are chemical species that are "nucleus-loving." They are characterized by having an abundance of electrons, which makes them electron-rich. - They must contain at least one lone pair of electrons. - Nucleophiles can be negatively charged or neutral. ...
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Knowledge Check

  • Which of the following acts as a nucleophile?

    A
    `CH_3 NH_2`
    B
    `overset(+)CH_3`
    C
    `AlCl_3`
    D
    `CH_3 MgBr`.
  • Which one of the following undergoes nucleophilic aromatic substitution at the fastest rate ?

    A
    B
    C
    D
  • Which of the following are correct order of nucleophilicity in CH_(3)OH

    A
    `overset(* *)NH_(3)ltoverset(* *)NH_(2)-overset(* *)NH_(2)`
    B
    `CH_(3)CH_(2)overset(ө)OgtOoverset(ө)HgtCH_(3)-overset(O)overset(||)C-overset(ө)O`
    C
    `F^(ө)gtCl^(ө)gtBr^(ө)gtI^(ө)`
    D
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    Which of the following is neutral nucleophile?

    Which of the following series contains nucleophiles only ?

    Which of the following has the highest nucleophilicity ?