Home
Class 12
CHEMISTRY
underset((A))(MeCH)=O+underset((B))(H(2)...

`underset((A))(MeCH)=O+underset((B))(H_(2)NOH) overset(HCOONa)underset(Delta)rarr (C )+H_(2)O` Product (C ) is:

A

B

C

`Me-C-=N`

D

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction between the given aldehyde (MeCH=O, which is acetaldehyde) and hydroxylamine (H2NOH) in the presence of sodium formate (HCOONa) and heat. The product (C) we are looking for is formed through a series of steps involving the formation of an oxime and then a subsequent reaction leading to a nitrile. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are acetaldehyde (MeCH=O) and hydroxylamine (H2NOH). 2. **Formation of Oxime**: - When acetaldehyde reacts with hydroxylamine, it undergoes nucleophilic addition. The nitrogen atom of hydroxylamine attacks the carbonyl carbon of acetaldehyde. - This results in the formation of an intermediate where the nitrogen is bonded to the carbon and the hydroxyl group (OH) is attached to the nitrogen, leading to the formation of an oxime. - The structure of the oxime formed is CH3C(=N-OH)H. 3. **Dehydration of Oxime**: - Upon heating, the oxime undergoes dehydration (loss of water). The hydroxyl group (OH) from the oxime and a hydrogen atom from the adjacent carbon are eliminated, forming a double bond between carbon and nitrogen. - This results in the formation of a nitrile (specifically, ethane nitrile or acetonitrile). 4. **Formation of Product (C)**: - The final product (C) is ethane nitrile (or acetonitrile), represented as CH3C≡N. 5. **Overall Reaction**: - The overall reaction can be summarized as: \[ \text{MeCH=O} + \text{H}_2\text{NOH} \xrightarrow{\text{HCOONa}, \Delta} \text{C (CH}_3\text{C}\equiv\text{N}) + \text{H}_2\text{O} \] ### Final Answer: The product (C) is **Ethane nitrile (CH3C≡N)**. ---

To solve the problem, we need to analyze the reaction between the given aldehyde (MeCH=O, which is acetaldehyde) and hydroxylamine (H2NOH) in the presence of sodium formate (HCOONa) and heat. The product (C) we are looking for is formed through a series of steps involving the formation of an oxime and then a subsequent reaction leading to a nitrile. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are acetaldehyde (MeCH=O) and hydroxylamine (H2NOH). 2. **Formation of Oxime**: ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion-Reasoning|6 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Objective|10 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct|33 Videos
  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Analytical And Descriptive|15 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos

Similar Questions

Explore conceptually related problems

RCH =CH_(2) overset((1)O_(3))underset((2)H_(2)O\\(Zn))(to)(A) overset(H_(2)O)underset(LiAIH_(4))(to)(B) Product (B) is

In the reaction sequence CH_(3)-overset(O)overset(||)(C)-H-underset(.^(Θ)OH)overset(HCN)rarr(A) underset(Delta)overset(H_(2)O //overset(o+)(H))rarr Product is/are :

Knowledge Check

  • Ph - CH_(2) - overset(O)overset(||)(C) - OH underset((2)H^(oplus))overset((1)NaOH,CaO,Delta)(rarr)(A) Product (A) is :

    A
    `Ph - CO_(2)H`
    B
    `Ph - CH_(2) - OH`
    C
    `Ph - CH_(3)`
    D
  • H_(3)C-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-H+C Cl_(4)underset(hv)overset(R_(2)O_(2))rarr"Product" :

    A
    `H_(3)C-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-Cl`
    B
    `CHCl_(3)`
    C
    Both (a) and (b)
    D
    None of these
  • Similar Questions

    Explore conceptually related problems

    underset("Tollen's test")underset("Gives positive")underset(darr)(C_(3)H_(6)O(A))overset(PhCHO)underset(OH^(-)//Delta)rarrB Product B is :

    {:(CH_(2)-CONH_(2)),("|"),(CH_(2)-CONH_(2)):} overset(P_(2)O_(5))underset(Delta)to(P) overset(H_(3)O^(o+))underset(Delta)to(Q) The product (Q) is

    Hoverset("dil NaOH")rarr[A]overset(H_(2)O^(+))underset(Delta)rarr[B]

    CH_(3)-underset(CH_3)underset(|)overset(CH_3)overset(|)(C )-underset(Br)underset(|)(C )H-CH_(3) underset(Delta)overset("El mechanism")(rarr) (A) Major product (A) is

    underset((A))("PhCOOMe") overset("(i)" NH_2 OH) underset("(ii)" overset (Ө)O H "(iii)" EtOH)rarr (B) Product (B) is :

    underset((A))(EtCOCl) overset((i)H_2 N.OH) underset ((ii) overset(Ө)O H) rarr (B) overset(EtOH) rarr (C) Which of the following statements are correct about the given reaction ?