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The Cannizzaro's reaction is not give by...

The Cannizzaro's reaction is not give by:

A

Trimethyl acetaldehyde

B

Acetaldehyde

C

Benzaldehyde

D

Formaldehyde

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To solve the question regarding the Cannizzaro reaction and identify which compound does not undergo this reaction, we can follow these steps: ### Step 1: Understand the Cannizzaro Reaction The Cannizzaro reaction is a redox reaction that occurs in aldehydes that do not have alpha-hydrogens. In this reaction, one molecule of the aldehyde is oxidized to a carboxylic acid, while another molecule is reduced to an alcohol. **Hint:** Remember that the presence of alpha-hydrogens is crucial for determining whether a compound can participate in the Cannizzaro reaction. ### Step 2: Identify the Compounds We need to analyze the given options to see which compound does not have alpha-hydrogens. The options are: 1. Trimethylacetaldehyde 2. Acetaldehyde 3. Benzaldehyde 4. Formaldehyde **Hint:** Look for the structure of each compound to identify the presence or absence of alpha-hydrogens. ### Step 3: Analyze Each Compound 1. **Trimethylacetaldehyde (C(CH3)3CHO)**: This compound has three methyl groups attached to the carbon adjacent to the carbonyl group. Therefore, it does not have any alpha-hydrogens. 2. **Acetaldehyde (CH3CHO)**: This compound has one alpha-hydrogen (the hydrogen on the methyl group). Therefore, it can participate in the Cannizzaro reaction. 3. **Benzaldehyde (C6H5CHO)**: This compound has no alpha-hydrogens because the carbonyl carbon is directly attached to a benzene ring. Thus, it can also undergo the Cannizzaro reaction. 4. **Formaldehyde (HCHO)**: This compound has no alpha-hydrogens and can participate in the Cannizzaro reaction. **Hint:** For each compound, check if the carbon adjacent to the carbonyl group has any hydrogen atoms. ### Step 4: Conclusion Based on the analysis: - Trimethylacetaldehyde has no alpha-hydrogens and can undergo the Cannizzaro reaction. - Acetaldehyde has alpha-hydrogens and can undergo the Cannizzaro reaction. - Benzaldehyde has no alpha-hydrogens and can undergo the Cannizzaro reaction. - Formaldehyde has no alpha-hydrogens and can undergo the Cannizzaro reaction. The only compound that does not undergo the Cannizzaro reaction is **Acetaldehyde**. ### Final Answer The Cannizzaro reaction is not given by: **Acetaldehyde** (Option 2).

To solve the question regarding the Cannizzaro reaction and identify which compound does not undergo this reaction, we can follow these steps: ### Step 1: Understand the Cannizzaro Reaction The Cannizzaro reaction is a redox reaction that occurs in aldehydes that do not have alpha-hydrogens. In this reaction, one molecule of the aldehyde is oxidized to a carboxylic acid, while another molecule is reduced to an alcohol. **Hint:** Remember that the presence of alpha-hydrogens is crucial for determining whether a compound can participate in the Cannizzaro reaction. ### Step 2: Identify the Compounds ...
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Knowledge Check

  • Cannizzaro reaction is not given by

    A
    trimethylacetaldehyde
    B
    acetaldehyde
    C
    benzaldehyde
    D
    formaldehyde.
  • Cannizzaro reaction is not given by

    A
    trimethylacetaldehyde
    B
    acetaldehyde
    C
    benzaldehyde
    D
    formaldehyde.
  • Cannizzaro reaction is not given by

    A
    trimethylacetaldehyde
    B
    acetaldehyde
    C
    benzaldehyde
    D
    formaldehyde.
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