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A first order reaction takes 40 min for ...

A first order reaction takes 40 min for 30% decomposition. What will be `t_(1//2)`?

A

`33.2 m i n `

B

`77.7 m i n`

C

`22.7 m i n`

D

`40 m i n `

Text Solution

Verified by Experts

The correct Answer is:
2

`30%` decomposition means that `x=30%` of `a=0.30a`
As reaction is of 1st order,
`k-(2.303)/(t)log.(a)/(a-x)=(2.303)/(40 min )log.(a)/(a-0.30a)=(2.303)/(40)xxlog.(10)/(7)"min"^(-1)`
For a 1st order reaction
`t_(1//2)=(0.693)/(k)=(0.693)/(8.918xx10^(-3)"min"^(-1))=77.7min`
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Knowledge Check

  • A first order reaction takes 40 min for 30% decomposition. Calculate t_(1//2) . (Given log 7 =0.845)

    A
    77.7 min
    B
    52.5 min
    C
    46.2min
    D
    22.7 min
  • For a first order reaction the rate constant for decomposition of N_(2)O is 6xx10^(-4)sec^(-1) . The half-life period for the decomposition in seconds is :

    A
    11.55
    B
    115.5
    C
    1155
    D
    1.155
  • Half life of a first order reaction in 10 min. What % of reaction will be completed in 100 min ?

    A
    0.25
    B
    0.5
    C
    0.999
    D
    0.75
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