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(a) Name the types of isomerrism shown b...

(a) Name the types of isomerrism shown by the following pairs of compounds:
(i) `[CoCl(H_(2)O)(NH_(3))_(4)]Cl_(2) and [CoCl_(2)(NH_(3))_(4)]Cl.H_(2)O`
(ii) `[Pt(NH_(3))_(4)]PtCl_(6)] and [Pt(NH_(3))_(4)Cl_(2)][PtCl_(4)]`.
(b) Write the IUPAC name of `[Co(en)_(2)Cl_(2)]^(+)` ion and draw the structure of its geometrical isomers.

A

linkage isomers

B

optical isomers

C

co-ordination isomers

D

ionisation isomers

Text Solution

Verified by Experts

The correct Answer is:
C
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What type of isomerism exists in the following pairs of complexes ? (i) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5) SO_(4) ] NO_(3) (ii) [Co(en)(H_(2)O)_(2) Cl_(2)] Cl and [Co(en) (H_(2)O) Cl_(3) ] H_(2)O

Knowledge Check

  • [Pt(NH_(3))_(4)][CuCl_(4)] and [Cu(NH_(3))_(4)][PtCl_(4)] are known as

    A
    ionisation isomers
    B
    coordination isomers
    C
    linkage isomers
    D
    polymerisation isomers.

  • What type of isomerism exists in the following pairs of complexes ? (i) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5) SO_(4) ] NO_(3) (ii) [Co(en)(H_(2)O)_(2) Cl_(2)] Cl and [Co(en) (H_(2)O) Cl_(3) ] H_(2)O

    A
    (i) Ionisation (ii) Hydrate
    B
    (i) Linkage (ii) Hydrate
    C
    (i) Ionisation (ii) Linkage
    D
    (i) Linkage (ii) Coordination