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A first order reaction is 50% complete i...

A first order reaction is 50% complete in 30 minutes at `27^@`C. Calculate the rate constant of the reaction at `27^@ `C.

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To solve the problem, we need to calculate the rate constant (k) for a first-order reaction that is 50% complete in 30 minutes at 27°C. ### Step-by-Step Solution: 1. **Understand the Concept of Half-Life in First-Order Reactions**: - For a first-order reaction, the half-life (t₁/₂) is the time taken for the concentration of the reactant to reduce to half its initial value. The relationship between the rate constant (k) and the half-life for a first-order reaction is given by the formula: \[ k = \frac{\ln(2)}{t_{1/2}} ...
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Knowledge Check

  • A first order reaction is 20% complete in 10 minutes. What is the specific rate constant for the reaction?

    A
    0.0970 `"min^(-1)`
    B
    0.009 `"min"^(-1)`
    C
    0.0223 `"min"^(-1)`
    D
    `2.223 "min"^(-1)`
  • ICSE-CHEMICAL KINETICS-ISC EXAMINATION QUESTIONS (NUMERICAL PROBLEMS )
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    2. The initial rate of a reaction A+B to Products is doubled when the co...

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    8. The rate constant of a first order reaction is 4.5 xx 10^(-2) sec^(-1)...

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    9. 1g of strontium - 90 was reduced to 0.953 g after two years. Calculate...

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    10. Show that the time required for the completion of 75% of a reaction of...

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    11. A study of chemical kinetics of the reaction, A+B to Products, gave t...

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    12. A study of chemical kinetics of the reaction, A+B to Products, gave t...

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    13. A study of chemical kinetics of the reaction, A+B to Products, gave t...

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    14. In a first order reaction, 10% of the reactant is consumed in 25 minut...

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    15. In a first order reaction, 10% of the reactant is consumed in 25 minut...

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    16. In a first order reaction, 10% of the reactant is consumed in 25 minut...

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    17. If the half-life period for a first order reaction is 69.3 seconds, wh...

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    18. The slope of the line in the graph of log k (k = rate constant) versus...

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    19. A substance decomposes by following first order kinetics. If 50% of th...

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    20. A first order reaction is 50% complete in 30 minutes at 27^@C. Calcula...

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