Home
Class 12
CHEMISTRY
Derive Nernst equation for the following...

Derive Nernst equation for the following cell:
`NiNi^(2+)(0*2M)||Cu^(2+)(0*2M)|Cu`.

Text Solution

Verified by Experts

`Ni//Ni^(2+)(0*2M)||Cu^(2+)(0*2M)|Cu`
The reaction involved an this cell are:
Oxidation: `Ni(s) to Ni^(2+)(aq)+2e^(-)`
Reduction: `Cu^(2+)(aq)+2e^(-) to Cu(s)`
Over all: `Cu^(2+)(aq)+Ni(s)toCu(s)+Ni^(2)(aq)`
Here n=2
`therefore`Nernst equator for the cell is,
`EMF=EMF^(@)-(2*303RT)/(nF)logQ_(C)`
`EMF=EMF^(@)-(0.0591)/(2)"log"([Ni^(2+)])/([Cu^(2+)])` at (298 K)
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    BETTER CHOICE PUBLICATION|Exercise FUEL CELLS|8 Videos
  • CO-ORDINATION COMPOUNDS

    BETTER CHOICE PUBLICATION|Exercise QUESTION FROM PREVIOUS BOARD EXAMINATION|59 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    BETTER CHOICE PUBLICATION|Exercise Question Bank (6.6 OXIDATION-REDUCTION)|15 Videos

Similar Questions

Explore conceptually related problems

Derive Nernst equation for the following cell: Cu|Cu^(2+)(0.1M)||Ag^(+)(0*1M)|Ag

Write Nernst equation and cell reaction of the following cell: Zn|Zn^(2+)||Cu^(2+)|Cu

Write the Nernst equation and emf of the following cells at 298 K: Mg(s)|Mg^(2+)(0.001M) || Cu^(2+)(0.0001 M)| Cu(s)

Write Nernst equation and calculate emf for the following cell: Zn|Zn^(2+)(0*01M)||Ag^(+)(0*01M)|Ag .

Write the Nernst equation and emf of the following cells at 298 K: Sn(s)|Sn^(2+)(0.050 M)||H^+(0.020 M)|H_2(g) (1 BAR)|Pt(s)

Write the Nernst equation and emf of the following cells at 298 K: Fe(s)|Fe^(2+)(0.001M) || H^+(1M) | H_2(g)( I BAR ) given Ecell = +0.44V

Give the Nernst equation of the cell: Ni(s)|NI^(2+)(aq)(0.1M)||Ag^(+)(aq)(0.1M)|Ag(s) and also find the cell potential. given that E^@(Ag^+|Ag)=0.80V, E^@(Ni^(2+)|Ni)=-0.25V

Write the Nernst equation and emf of the following cells at 298 K: Br^-(0.010 M)|Br_2(l ) || H^+(0.030 M)| H_2(g) (1 BAR )|Pt(s) .

BETTER CHOICE PUBLICATION-ELECTROCHEMISTRY-Numerical Problems
  1. Derive Nernst equation for the following cell: NiNi^(2+)(0*2M)||Cu^(...

    Text Solution

    |

  2. Derive Nernst equation for the following cell: Cu|Cu^(2+)(0.1M)||Ag^...

    Text Solution

    |

  3. Write Nernst equation and calculate emf for the following cell: Zn|Z...

    Text Solution

    |

  4. Calculate DeltaG^(@) and equilibrium constant for the cell reaction, ...

    Text Solution

    |

  5. A potential difference of 20 V applied to the ends of a column of 0.1 ...

    Text Solution

    |

  6. For the cell Mg|Mg^(2+)||Ag^(+)|Ag calculate equilibrium constant at 2...

    Text Solution

    |

  7. The electrical resistance of a column of 0.05 mol L^(-1) NaOH solution...

    Text Solution

    |

  8. A conductivity cell has its electrodes 1 cm apart and each electrode h...

    Text Solution

    |

  9. Calculate DeltaG^(@) for the following cell: Fe|Fe^(2+)||Cu^(2+)|Cu....

    Text Solution

    |

  10. E^(@) values for Fe^(3+)//Fe^(2+) and Ag^(+)//Ag are 0.771 V and 0.8 r...

    Text Solution

    |

  11. The resistance of a 0.5 M solution of an electrolyte enclosed between ...

    Text Solution

    |

  12. E^(@) value for Cu^(2+)//Cu and Fe^(2+)//Fe are +0.34 V and -0.44 V re...

    Text Solution

    |

  13. A 0.05 M NaOH solution offered a resistance of 31.6 ohm ina conductivi...

    Text Solution

    |

  14. E^(@) values of Ni^(2+)//Ni and Cu^(2+)//Cu are -0.25 V and +0.34 V re...

    Text Solution

    |

  15. The resistance of a 0.5 M solution of an electrolyte in a conductivity...

    Text Solution

    |

  16. Represent the cell in which the following reaction takes place Mg(s) +...

    Text Solution

    |

  17. Represent the cell in which the following reaction takes place: Mg(s...

    Text Solution

    |

  18. Write Nernst equation and calculate the e.m.f. of the following cell a...

    Text Solution

    |

  19. The molar conductance of NaCl solution at different concentrations at ...

    Text Solution

    |

  20. Write Nernst equation and calculate e.m.f. of the cell at 298 k. Mg(...

    Text Solution

    |