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Which is true about different forms of h...

Which is true about different forms of hydrogen :

A

ortho hydrogen has same spins of two nuclei clockwise or anticlockwise

B

para hydrogen has different spins of two nuclei

C

at absolute zero, there is `100%` para form and at high temperature, there is `75%` ortho form

D

all are correct.

Text Solution

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The correct Answer is:
To determine which statements about the different forms of hydrogen are true, we need to analyze the properties of ortho and para hydrogen. ### Step-by-Step Solution: 1. **Understanding the Forms of Hydrogen**: - Dihydrogen (H₂) exists in two forms: ortho and para hydrogen. These are known as nuclear spin isomers. 2. **Defining Ortho and Para Hydrogen**: - **Ortho Hydrogen**: In this form, the spins of the two hydrogen nuclei (protons) are aligned in the same direction (both clockwise or both anticlockwise). This means they have a net spin of 1. - **Para Hydrogen**: In this form, the spins of the two hydrogen nuclei are opposite (one clockwise and one anticlockwise). This results in a net spin of 0. 3. **Stability of the Forms**: - Para hydrogen is more stable than ortho hydrogen because the opposing spins cancel each other out, leading to a lower energy state. 4. **Behavior at Absolute Zero**: - At absolute zero (0 Kelvin), only para hydrogen exists. This is because thermal energy is insufficient to maintain the ortho form. 5. **Analyzing the Statements**: - **Statement 1**: "Ortho hydrogen has the same spins of nuclei (clockwise or anticlockwise)." - This is **true**. - **Statement 2**: "Para hydrogen has different spins of two nuclei." - This is **true**. - **Statement 3**: "At absolute zero, there is 100% para form." - This is **true**. - **Statement 4**: "At high temperature, there is 75% ortho form." - This is **false**. The distribution of ortho and para forms does not depend on temperature in a straightforward manner; rather, it is a function of the equilibrium between the two forms. ### Conclusion: - The true statements about different forms of hydrogen are: - Statement 1: True - Statement 2: True - Statement 3: True - Statement 4: False ### Final Answer: Statements 1, 2, and 3 are true, while statement 4 is false. ---

To determine which statements about the different forms of hydrogen are true, we need to analyze the properties of ortho and para hydrogen. ### Step-by-Step Solution: 1. **Understanding the Forms of Hydrogen**: - Dihydrogen (H₂) exists in two forms: ortho and para hydrogen. These are known as nuclear spin isomers. 2. **Defining Ortho and Para Hydrogen**: ...
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