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Statement 1: A solution of sucrose in wa...

Statement 1: A solution of sucrose in water is dextrorotatory but on hydrolysis in presence of little hydrochloride acid, it becomes laevorotatory.
Statement 2: Sucrose on hydrolysis gives unequal amounts of glucose and fructose as a result of which change in sign of rotation is observed.

A

Statement 1 is True, Statement 2 is True, Statement 2 is Correct explanation for Statement 1.

B

Statement 1 is True, Statement 2 is True, Statement 2 is NOT a correct explanation for Statement 1.

C

Statement 1 is True, Statement 2 is False.

D

Statement 1 is False, Statement 2 is True.

Text Solution

Verified by Experts

The correct Answer is:
C

Sucrose on hydrolysis gives equal amounts of glucose and fructose. Since glucose has less positive and fructose has more negative magnitude of rotation, therefore, change in sign of rotation is observed.
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Knowledge Check

  • Each of these questions contains two statements: Statement 1 and Statement2. Each of these questions has four alternative choices, only one of which is the correct answer. Statment 1 : S_N2 reaction of an optically active aryl halide with an aqueous solution of KOH always gives an alcohol with opposite sign of rotation. Statement 2: S_N2 reactions always proceed with inversion of configuration

    A
    Statement 1 is True, Statement 2 is True, Statement 2 is Correct explanation for Statement 1.
    B
    Statement 1 is True, Statement 2 is True, Statement 2 is NOT a correct explanation for Statement 1.
    C
    Statement 1 is True, Statement 2 is False.
    D
    Statement 1 is False, Statement 2 is True.
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    A
    I, II and III
    B
    I and IV
    C
    II and III and IV
    D
    II and IV
  • Statement 1 : AICI_3 forms dimer AlCl_6 but dissolves in water to form [Al(H_2O)_6]^(3+) and Cl^(Theta) ions. Statement 2 : Aqueous solution of AICI_3 is acidic due to hydrolysis.

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    Statement 1 is True, statement 2 is True, Statement 2 is Correct explanation for Statement 1.
    B
    Statement 1 is True, Statement 2 is True, Statement 2 is NOT a correct explanation for Statement 1.
    C
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