Hydrogen peroxide can be preapared by the action of dil. `H_(2)SO_(4)` or `H_(3)PO_(4)` on barium peroxide or by bubbling peroxide . On an industrial scale, it can be prepared by hydrolysis of peroxodisulphuric acid obtained by electrolysis of 50% `H_(2)SO_(4)` or an equimolar mixture of `H_(2)SO_(4)` and ammonium sulphate . The strength of `H_(2)O_(2)` solution can be expressed in a number of ways namely normality , molarity , percentage strength and volume strength . Volume strength refers to the volume of `O_(2)` produced at N.T.P. by decomposition of 1 mL of `H_(2)O_(2)` solution. `H_(2)O_(2)` acts as an oxidising as well as reducing agent both in acidic and basic media.
The correct increasing order of the acidity of `CO_(2), H_(2)O and H_(2)O_(2)` is
Hydrogen peroxide can be preapared by the action of dil. `H_(2)SO_(4)` or `H_(3)PO_(4)` on barium peroxide or by bubbling peroxide . On an industrial scale, it can be prepared by hydrolysis of peroxodisulphuric acid obtained by electrolysis of 50% `H_(2)SO_(4)` or an equimolar mixture of `H_(2)SO_(4)` and ammonium sulphate . The strength of `H_(2)O_(2)` solution can be expressed in a number of ways namely normality , molarity , percentage strength and volume strength . Volume strength refers to the volume of `O_(2)` produced at N.T.P. by decomposition of 1 mL of `H_(2)O_(2)` solution. `H_(2)O_(2)` acts as an oxidising as well as reducing agent both in acidic and basic media.
The correct increasing order of the acidity of `CO_(2), H_(2)O and H_(2)O_(2)` is
The correct increasing order of the acidity of `CO_(2), H_(2)O and H_(2)O_(2)` is
A
`CO_(2) lt H_(2)O_(2) lt H_(2)O`
B
`H_(2)Olt H_(2)O_(2) lt CO_(2)`
C
`H_(2)O lt H_(2)O_(2) gt CO_(2)`
D
`H_(2)O_(2) gt CO_(2) gt H_(2)O`
Text Solution
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The correct Answer is:
To determine the increasing order of acidity for CO₂, H₂O, and H₂O₂, we can analyze the acidic properties of each compound step by step.
### Step 1: Understanding the Compounds
- **CO₂ (Carbon Dioxide)**: When CO₂ dissolves in water, it forms carbonic acid (H₂CO₃), which is a weak acid. This indicates that CO₂ can contribute to acidity when in solution.
- **H₂O (Water)**: Water is amphoteric, meaning it can act as both an acid and a base. However, it is generally considered neutral and has a very weak acidic nature.
- **H₂O₂ (Hydrogen Peroxide)**: Hydrogen peroxide is also a weak acid, but it is less acidic than carbonic acid.
### Step 2: Comparing Acidity
- **CO₂**: Forms carbonic acid in solution, which is more acidic than water and hydrogen peroxide.
- **H₂O₂**: Acts as a weak acid but is less acidic than carbonic acid. It is more acidic than water.
- **H₂O**: Generally neutral and has the least acidic character among the three.
### Step 3: Establishing the Order
From the analysis:
- CO₂ is the most acidic because it forms carbonic acid.
- H₂O₂ is more acidic than H₂O but less acidic than CO₂.
- H₂O is the least acidic.
### Conclusion
Thus, the correct increasing order of acidity is:
**H₂O < H₂O₂ < CO₂**
To determine the increasing order of acidity for CO₂, H₂O, and H₂O₂, we can analyze the acidic properties of each compound step by step.
### Step 1: Understanding the Compounds
- **CO₂ (Carbon Dioxide)**: When CO₂ dissolves in water, it forms carbonic acid (H₂CO₃), which is a weak acid. This indicates that CO₂ can contribute to acidity when in solution.
- **H₂O (Water)**: Water is amphoteric, meaning it can act as both an acid and a base. However, it is generally considered neutral and has a very weak acidic nature.
- **H₂O₂ (Hydrogen Peroxide)**: Hydrogen peroxide is also a weak acid, but it is less acidic than carbonic acid.
### Step 2: Comparing Acidity
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Hydrogen peroxide can be preapared by the action of dil. H_(2)SO_(4) or H_(3)PO_(4) on barium peroxide or by bubbling peroxide . On an industrial scale, it can be prepared by hydrolysis of peroxodisulphuric acid obtained by electrolysis of 50% H_(2)SO_(4) or an equimolar mixture of H_(2)SO_(4) and ammonium sulphate . The strength of H_(2)O_(2) solution can be expressed in a number of ways namely normality , molarity , percentage strength and volume strength . Volume strength refers to the volume of O_(2) produced at N.T.P. by decomposition of 1 mL of H_(2)O_(2) solution. H_(2)O_(2) acts as an oxidising as well as reducing agent both in acidic and basic media. Hydrolysis of one mole of peroxodisulphuric acid produces
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Hydrogen can be prepared by the action of dil. H_(2)SO_(4) on
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Hydrogen peroxide can be preapared by the action of dil. H_(2)SO_(4) or H_(3)PO_(4) on barium peroxide or by bubbling peroxide . On an industrial scale, it can be prepared by hydrolysis of peroxodisulphuric acid obtained by electrolysis of 50% H_(2)SO_(4) or an equimolar mixture of H_(2)SO_(4) and ammonium sulphate . The strength of H_(2)O_(2) solution can be expressed in a number of ways namely normality , molarity , percentage strength and volume strength . Volume strength refers to the volume of O_(2) produced at N.T.P. by decomposition of 1 mL of H_(2)O_(2) solution. H_(2)O_(2) acts as an oxidising as well as reducing agent both in acidic and basic media. 100 volume hydrogen peroxide solution means
Hydrogen peroxide can be preapared by the action of dil. H_(2)SO_(4) or H_(3)PO_(4) on barium peroxide or by bubbling peroxide . On an industrial scale, it can be prepared by hydrolysis of peroxodisulphuric acid obtained by electrolysis of 50% H_(2)SO_(4) or an equimolar mixture of H_(2)SO_(4) and ammonium sulphate . The strength of H_(2)O_(2) solution can be expressed in a number of ways namely normality , molarity , percentage strength and volume strength . Volume strength refers to the volume of O_(2) produced at N.T.P. by decomposition of 1 mL of H_(2)O_(2) solution. H_(2)O_(2) acts as an oxidising as well as reducing agent both in acidic and basic media. 100 volume hydrogen peroxide solution means
A
17.86 N
B
30.36% `H_(2)O_(2)`
C
`8.93 M`
D
all are correct
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Hydrogen peroxide can be preapared by the action of dil. H_(2)SO_(4) or H_(3)PO_(4) on barium peroxide or by bubbling peroxide . On an industrial scale, it can be prepared by hydrolysis of peroxodisulphuric acid obtained by electrolysis of 50% H_(2)SO_(4) or an equimolar mixture of H_(2)SO_(4) and ammonium sulphate . The strength of H_(2)O_(2) solution can be expressed in a number of ways namely normality , molarity , percentage strength and volume strength . Volume strength refers to the volume of O_(2) produced at N.T.P. by decomposition of 1 mL of H_(2)O_(2) solution. H_(2)O_(2) acts as an oxidising as well as reducing agent both in acidic and basic media. Which of the following substances on treatment with H_(2)O_(2) gives MnO_(2)
Hydrogen peroxide can be preapared by the action of dil. H_(2)SO_(4) or H_(3)PO_(4) on barium peroxide or by bubbling peroxide . On an industrial scale, it can be prepared by hydrolysis of peroxodisulphuric acid obtained by electrolysis of 50% H_(2)SO_(4) or an equimolar mixture of H_(2)SO_(4) and ammonium sulphate . The strength of H_(2)O_(2) solution can be expressed in a number of ways namely normality , molarity , percentage strength and volume strength . Volume strength refers to the volume of O_(2) produced at N.T.P. by decomposition of 1 mL of H_(2)O_(2) solution. H_(2)O_(2) acts as an oxidising as well as reducing agent both in acidic and basic media. Which of the following substances on treatment with H_(2)O_(2) gives MnO_(2)
A
acidified `KMnO_(4)`
B
alkaline `KMnO_(4)`
C
alkaline `MnSO_(4)`
D
both (b) and (c)
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Hydrogen peroxide can be preapared by the action of dil. H_(2)SO_(4) or H_(3)PO_(4) on barium peroxide or by bubbling peroxide . On an industrial scale, it can be prepared by hydrolysis of peroxodisulphuric acid obtained by electrolysis of 50% H_(2)SO_(4) or an equimolar mixture of H_(2)SO_(4) and ammonium sulphate . The strength of H_(2)O_(2) solution can be expressed in a number of ways namely normality , molarity , percentage strength and volume strength . Volume strength refers to the volume of O_(2) produced at N.T.P. by decomposition of 1 mL of H_(2)O_(2) solution. H_(2)O_(2) acts as an oxidising as well as reducing agent both in acidic and basic media. The volume of 10 volume H_(2)O_(2) solution that decolourises 200 mL of 2N KMnO_(4) solution in acidic medium is :
Hydrogen peroxide can be preapared by the action of dil. H_(2)SO_(4) or H_(3)PO_(4) on barium peroxide or by bubbling peroxide . On an industrial scale, it can be prepared by hydrolysis of peroxodisulphuric acid obtained by electrolysis of 50% H_(2)SO_(4) or an equimolar mixture of H_(2)SO_(4) and ammonium sulphate . The strength of H_(2)O_(2) solution can be expressed in a number of ways namely normality , molarity , percentage strength and volume strength . Volume strength refers to the volume of O_(2) produced at N.T.P. by decomposition of 1 mL of H_(2)O_(2) solution. H_(2)O_(2) acts as an oxidising as well as reducing agent both in acidic and basic media. The volume of 10 volume H_(2)O_(2) solution that decolourises 200 mL of 2N KMnO_(4) solution in acidic medium is :
A
112 mL
B
336 mL
C
200 mL
D
224 mL
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