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Why carbon froms covalent compounds wher...

Why carbon froms covalent compounds whereas lead forms ionic compounds ?

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Carbon cannot lose all the four valence electrons to form `C^(4+)` ions because the sum of the first four ioniatization enthalpies of carbon is very large. It also cannot gain four electron to form `C^(4-)` ion as their anion would be highly unstable because it would be very difficult for a nucleus with only 6 protons to hold on family 10 electrons. Therefore, carbon forms only covalent compounds by sharing of electrons:
In contrast due to inert pair effect, +2 oxidation state of Pb is more stable thanits +4 oxidation state.
Further on moving down the group, the ionization enthalpy decreases. As a result , the sum of the first two ionization enthalpies of Pb is quite low and hence Pb can easily lose two electrons to form `Pb^(2+)` ions.
Consequently, Pb form ionic compounds.
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PRADEEP-SOME p-BLOCK ELEMENTS-CONCEPTUAL QUESTIONS (GROUP 14 ELEMENTS)
  1. Tendency to exhibit +2 oxidation state increases with increasing atom...

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  2. Why is+2oxidiation state of lead more stable than +4 oxidation state?

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  3. Why carbon froms covalent compounds whereas lead forms ionic compounds...

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  4. Give one chemical reaction to show that : (i) Sn(II) is a reducing a...

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  5. PbO2 acts as a stronger oxidising agent than SnO2. Cmment .

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  6. PbO(2) can act as an oxidising agent.

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  7. Carbon monoxide is readily absorbed by ammoniacal cuprous chloride so...

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  8. CO is stable , but analogous SiO is not stable . Why ?

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  9. Why N(CH(3))(3) is pyramidal but N(SiH(3))(3) is planar ?

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  10. (SiH(3)) is a weaker base than (CH(3))(3)N. Explain.

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  11. Why N(CH(3))(3) is more basic than N(SiMe(3))(3) ?

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  12. Account for the following : (i) PbX(2) is more stable than PbX(4) (X ...

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  13. Why C Cl4 is resistant to hydrolysis , but SiCl4 is readily hudrolgyse...

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  14. The tendency towards catenation among group 14 elements down the group

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  15. why carbon show catenation but silicon does not ?

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  16. Give reason : Down the group tendency for catenation decreases among g...

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  17. Silanes are few in number whereas alkanes are large in number . Explai...

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  18. Why does not sillicon form an analogue of graphite?

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  19. Why does elemental silicon not form graphite like structure as carb...

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  20. No form fo elecmental silicon is comparabnle to graphite Give reason .

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