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Standard electrode potential values, E^...

Standard electrode potential values, `E^(@)` at `Al^(3+)//Al` is `-1.66 V` and that of `Tl^(3+)//Tl` is `+1.26 V`. Predict about the formation of `M^(3+)` ions in solution and compare the electropositive character of the two metals.

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To analyze the formation of \( M^{3+} \) ions in solution and compare the electropositive character of aluminum (Al) and thallium (Tl), we can follow these steps: ### Step 1: Understand the Standard Electrode Potential Values The standard electrode potential values given are: - For aluminum: \( E^\circ (Al^{3+}/Al) = -1.66 \, V \) - For thallium: \( E^\circ (Tl^{3+}/Tl) = +1.26 \, V \) ### Step 2: Predict the Formation of \( M^{3+} \) Ions ...
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(a) Standard electrode potential value E^@ for Al^(3+)//Al is - 1.66 V and that of Tl^(3+)//Tl is + 1.26 V . Predict about the formation of M^(3+) ion in solution and compare the electropositive character of the two metals. (b) White fumes appear around the bottle of anhydrous aluminium chloride. Give reason. ( c) Boron is unable to form BF_(6)^(3-) ion. Explain.

Standard electrode potential Au^(+3)//Au couple is 1.428 V and that for Na^(+)//Na couple -2.714 V These two couples in their standard state are connected to make a cell. The cell potential will be :-

Identity the correct statement (s) based on the folowing standard electrode potential (E^(0) value: E^(0)_(AI^(3+))//AI=-1.66V,E^(0)_(TI^(3+))//TI=+1.26V I. Aluminium has least tendency to make AI^(3+) (aq)ions II TI^(+) is unstable in solution and is a powerful oxidizing agent III TI^(+) is more stable in solution than TI^(3+) IV TI is more electropositive than AI

The standard electrode potential (reduction) of Ag^(+)|Ag is 0.800 V at 25^(@)C . Its electrode potential in a solution containing 10^(-3)M ion of Ag^(+) ions is:-

Standard electrode potential of three metal X, Y and Z are -1.2 V, +0.5 V and -3.0 V respectively. The reducing power of these metals will be:

E_(Al^(3+)//Al)^(@)=-1.66 V and K_(SP) of Al(OH)_(3)=1.0xx10^(-33) . Reduction potential of the above couple at pH=14 is :

E_(Al^(3+)//Al)^(*)=-1.66V and K_(SP) of Al(OH)_(3)=1.0xx10^(-33) . Reduction potential of the above couple at pH =14 is :

Knowledge Check

  • Standard electrode potential Au^(+3)//Au couple is 1.428 V and that for Na^(+)//Na couple -2.714 V These two couples in their standard state are connected to make a cell. The cell potential will be :-

    A
    4.142
    B
    1.286V
    C
    `-1.286 V`
    D
    `3.376 V`
  • Identity the correct statement (s) based on the folowing standard electrode potential (E^(0) value: E^(0)_(AI^(3+))//AI=-1.66V,E^(0)_(TI^(3+))//TI=+1.26V I. Aluminium has least tendency to make AI^(3+) (aq)ions II TI^(+) is unstable in solution and is a powerful oxidizing agent III TI^(+) is more stable in solution than TI^(3+) IV TI is more electropositive than AI

    A
    I and IV only
    B
    II only
    C
    II and III only
    D
    I and III only
  • The standard electrode potential (reduction) of Ag^(+)|Ag is 0.800 V at 25^(@)C . Its electrode potential in a solution containing 10^(-3)M ion of Ag^(+) ions is:-

    A
    `0.623V`
    B
    `-0.977V`
    C
    `0.892V`
    D
    `1.246V`
  • PRADEEP-SOME p-BLOCK ELEMENTS-NCERT QUESTIONS AND EXERCISES WITH ANSWERS (NCERT INTEXT SOLVED QUESTIONS)
    1. Standard electrode potential values, E^(@) at Al^(3+)//Al is -1.66 V ...

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    2. White fumes appear around the bottle of anhydrous aluminium chloride. ...

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    3. Boron is unable to form BF(6)^(3-)– ion. Explain.

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    4. Why is boric acid considered as a weak acid ?

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    5. In elements of group 14. (a) which forms the most acidic oxide (b)...

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    6. [SiF(6)]^(2-) is known where as [SiCl(6)]^(2-) not. Reason is

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    7. Diamond is covalent, yet it has high melting point. Why ?

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    8. What are silicones ?

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    9. What happens when (a) Borax is heated strongly, (b) Boric acid is ...

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    10. Explain the following reactions (a) Silicon is heated with methyl ch...

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    11. Give reasons : (i) Conc. HNO(3) can be transported in aluminium con...

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    12. Explain why is there a phenomenal decrease in ionisation enthalpy from...

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    13. How would you explain the lower atomic radii of Ga as compared to Al?

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    14. What are allotropes? Sketch the structure of two allotropes of carbon ...

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    15. a. Classify following oxides as neutral, acidic, basic or amphoteric: ...

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    16. In some of the reactions, thallium resembles aluminium whereas in othe...

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    17. When metal X is treated with sodium hydroxide, a white precipitate (A)...

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    18. What do you understand by (a) inert pair effect (b) allotropy and (c...

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    19. A certain salt X gives the following results: (i) Its aqueous soluti...

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    20. Write balanced equations for the following: (i) BF(3)+LiHrarr (ii) B...

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