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Standard electrode potential values, E^...

Standard electrode potential values, `E^(@)` at `Al^(3+)//Al` is `-1.66 V` and that of `Tl^(3+)//Tl` is `+1.26 V`. Predict about the formation of `M^(3+)` ions in solution and compare the electropositive character of the two metals.

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To analyze the formation of \( M^{3+} \) ions in solution and compare the electropositive character of aluminum (Al) and thallium (Tl), we can follow these steps: ### Step 1: Understand the Standard Electrode Potential Values The standard electrode potential values given are: - For aluminum: \( E^\circ (Al^{3+}/Al) = -1.66 \, V \) - For thallium: \( E^\circ (Tl^{3+}/Tl) = +1.26 \, V \) ### Step 2: Predict the Formation of \( M^{3+} \) Ions ...
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(a) Standard electrode potential value E^@ for Al^(3+)//Al is - 1.66 V and that of Tl^(3+)//Tl is + 1.26 V . Predict about the formation of M^(3+) ion in solution and compare the electropositive character of the two metals. (b) White fumes appear around the bottle of anhydrous aluminium chloride. Give reason. ( c) Boron is unable to form BF_(6)^(3-) ion. Explain.

The standard electrode potential corresponding to the reaction : Au^(3+)(aq) +3e^(-) rarrAu(s) is 1.42 V . Predict (i) if gold can be can be dissolved in 1 M HCl solution and (ii) on passing hydrogen gas through gold solt solution, metallic gold will be precipitated or not .

Knowledge Check

  • Standard electrode potential Au^(+3)//Au couple is 1.428 V and that for Na^(+)//Na couple -2.714 V These two couples in their standard state are connected to make a cell. The cell potential will be :-

    A
    4.142
    B
    1.286V
    C
    `-1.286 V`
    D
    `3.376 V`
  • Identity the correct statement (s) based on the folowing standard electrode potential (E^(0) value: E^(0)_(AI^(3+))//AI=-1.66V,E^(0)_(TI^(3+))//TI=+1.26V I. Aluminium has least tendency to make AI^(3+) (aq)ions II TI^(+) is unstable in solution and is a powerful oxidizing agent III TI^(+) is more stable in solution than TI^(3+) IV TI is more electropositive than AI

    A
    I and IV only
    B
    II only
    C
    II and III only
    D
    I and III only
  • The standard electrode potential (reduction) of Ag^(+)|Ag is 0.800 V at 25^(@)C . Its electrode potential in a solution containing 10^(-3)M ion of Ag^(+) ions is:-

    A
    `0.623V`
    B
    `-0.977V`
    C
    `0.892V`
    D
    `1.246V`
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