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Why N(CH(3))(3) is pyramidal but N(SiH(3...

Why `N(CH_(3))_(3)` is pyramidal but `N(SiH_(3))_(3)` is planar ?

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To understand why \( N(CH_3)_3 \) is pyramidal while \( N(SiH_3)_3 \) is planar, we need to analyze the molecular geometry and hybridization of both compounds. ### Step-by-Step Solution: **Step 1: Analyze \( N(CH_3)_3 \)** - **Structure**: The nitrogen atom in \( N(CH_3)_3 \) is bonded to three methyl groups (CH₃) and has one lone pair of electrons. - **Hybridization**: To determine the hybridization, we count the number of lone pairs and bonded pairs: - Lone pairs = 1 ...
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(CH_(3))_(3) N is

Trisilyamine (SiH_(3))_(3) N is

Assertion In case of (CH_(3))_(3)N geometry is pyramidal but in case of (SiH_(3))_(3)N it is planar Reasoning The maximum covalency of Si is six but that of C is four .

Both N(SiH_(3))_(3) and NH(SiH_(3))_(2) compounds have trigonal planar skeleton. Incorrect statement about both compounds is :

PRADEEP-SOME p-BLOCK ELEMENTS-CONCEPTUAL QUESTIONS (GROUP 14 ELEMENTS)
  1. Why is+2oxidiation state of lead more stable than +4 oxidation state?

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  2. Why carbon froms covalent compounds whereas lead forms ionic compounds...

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  3. Give one chemical reaction to show that : (i) Sn(II) is a reducing a...

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  4. PbO2 acts as a stronger oxidising agent than SnO2. Cmment .

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  5. PbO(2) can act as an oxidising agent.

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  6. Carbon monoxide is readily absorbed by ammoniacal cuprous chloride so...

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  7. CO is stable , but analogous SiO is not stable . Why ?

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  8. Why N(CH(3))(3) is pyramidal but N(SiH(3))(3) is planar ?

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  9. (SiH(3)) is a weaker base than (CH(3))(3)N. Explain.

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  10. Why N(CH(3))(3) is more basic than N(SiMe(3))(3) ?

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  11. Account for the following : (i) PbX(2) is more stable than PbX(4) (X ...

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  12. Why C Cl4 is resistant to hydrolysis , but SiCl4 is readily hudrolgyse...

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  13. The tendency towards catenation among group 14 elements down the group

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  14. why carbon show catenation but silicon does not ?

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  15. Give reason : Down the group tendency for catenation decreases among g...

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  16. Silanes are few in number whereas alkanes are large in number . Explai...

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  17. Why does not sillicon form an analogue of graphite?

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  18. Why does elemental silicon not form graphite like structure as carb...

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  19. No form fo elecmental silicon is comparabnle to graphite Give reason .

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  20. CO(2) is a gas while SiO(2) is a solid. Explain.

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