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Statement-1. Toluene on sulphonation giv...

Statement-1. Toluene on sulphonation gives m-toluenesulfonic acid.
Statement-2. Sulphonation is a reversible reaction.

A

Statement-1 is True, Statement-2 is True , Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True , Statement-2 is not a correct explanation for Statement-1

C

Statement- 1 is True, Statement-2 is False

D

Statement-1 is False, Statement -2 is True

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze both statements regarding the sulphonation of toluene. ### Step-by-Step Solution: 1. **Understanding Toluene and Sulphonation**: - Toluene (C6H5CH3) is an aromatic hydrocarbon that contains a methyl group (-CH3) attached to a benzene ring. - Sulphonation is the process of introducing a sulfonyl group (-SO3H) into an organic compound, typically through the reaction of the compound with sulfuric acid or sulfur trioxide. 2. **Determining the Product of Toluene Sulphonation**: - When toluene undergoes sulphonation, the sulfonyl group can attach to the benzene ring at different positions: ortho (adjacent to the methyl group), meta (one carbon away), or para (opposite to the methyl group). - The methyl group is an activating group and directs electrophilic substitution to the ortho and para positions. Therefore, the sulfonation of toluene primarily yields ortho- and para-toluenesulfonic acids. 3. **Evaluating Statement-1**: - Statement-1 claims that toluene on sulphonation gives m-toluenesulfonic acid. - This statement is **false** because the major products are ortho- and para-toluenesulfonic acids, not meta-toluenesulfonic acid. 4. **Evaluating Statement-2**: - Statement-2 states that sulphonation is a reversible reaction. - This statement is **true** because the sulfonic acid group can be removed under certain conditions, making the reaction reversible. 5. **Conclusion**: - Statement-1 is false, and Statement-2 is true. ### Final Answer: - Statement-1: False - Statement-2: True

To solve the question, we will analyze both statements regarding the sulphonation of toluene. ### Step-by-Step Solution: 1. **Understanding Toluene and Sulphonation**: - Toluene (C6H5CH3) is an aromatic hydrocarbon that contains a methyl group (-CH3) attached to a benzene ring. - Sulphonation is the process of introducing a sulfonyl group (-SO3H) into an organic compound, typically through the reaction of the compound with sulfuric acid or sulfur trioxide. ...
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