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Reaction With Phosphorus Halides...

Reaction With Phosphorus Halides

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On reaction with Cl_(2) phosphorus forms two types of halides 'A' and 'B'. Halide 'A' is yellowish- white powder but halide 'B' is colourless oily liquid. Identify A and B and write the formulae of their hydrolysis products.

Knowledge Check

  • The reaction of white phosphorus with aqueous NaOH gives phosphine along with another phosphorus containing compound. The reaction type , the oxidation states of phosphorus in phosphine and the other product are respectively

    A
    redox reaction , –3 and –5
    B
    redox reaction , +3 and +5
    C
    disproportionation reaction , –3 and +1
    D
    disproportionation reaction , –3 and +3