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What is "molecularity" of a reaction ? H...

What is "molecularity" of a reaction ? How is it different from the 'order' of a reaction? Name one bimolecular and one trimolecular gaseous reactions.

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The number of reacting species (atoms, ions or molecules) taking parts in an elementary reaction, which must colloid simultaneously to bring about a chemical reaction is called molecularity of a reaction.
`NH_(4)NO_(2)to N_(2)+ 2H_(2)O` (Unimolecular
`2HI to H_(2)+ I_(2)` (Bimolecular)
`2NO + O_(2)to 2NO_(2)` (Trimolecular)
`to` Molecularity has only integer values `(1,2,3........)`
`to ` It has non zero, non fractio values while order has zero `1,2,3..........` and fractional values.
`to` It is determined by reaction mechanism, order is determined experimentally.
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Knowledge Check

  • If the rate of gaseous reaction is independent of pressure, the order of reaction is

    A
    0
    B
    1
    C
    2
    D
    3
  • If the rate of gaseous reaction is independent of pressure, the order of raction is

    A
    0
    B
    1
    C
    2
    D
    3
  • Which one of the following statements for the order of a reaction is incorrect ?

    A
    Order of reaction is always whole number
    B
    Order can be determined only experimentally
    C
    Order is not influenced by stoichiometric coefficient of the reactants
    D
    Order of reaction is sum of powers to the concentration terms of reactants to express the rate of reaction.
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    What is Zero Order reaction ?

    Describe the salient features of the collision theory of reaction rates of bimolecular reactions.