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Ultraviolet light of wavelength 800 A an...

Ultraviolet light of wavelength `800 A` and `700 A` when allowed to fall on hydrogen atoms in their ground states is found to liberate electrons with kinetic energies `1.8eV` and `4.0eV`, respectively. Find the value of Planck's constant.

Text Solution

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The energy of incident photon `= (hc//lambda)`
If `W`, is the ionization energy and `E_(K)` the kinetic energy of the emitted electrons , then we have
`(hc)/(lambda_(1)) = W_(i) + E_(K)`
For incident of wavelength `lambda_(1) = 800 Å = 8 xx 10^(-8) m`,
`(hc)/(lambda_(1)) = W_(i) + E_(K_1)` ...(i)
and for incident of wavelength `lambda_(2) = 700 Å = 7 xx 10^(-8) m`
`(hc)/(lambda_(2)) = W_(i) + E_(K_2)` ...(ii)
Subtracting Eq. (i) from Eq (ii) we get `((1)/(lambda_(2))/(1)/(lambda_(1))) = E_(K_2) - E_(K_1)`
or `h = (( E_(K_2) - E_(K_1)) lambda_(1) lambda_(2))/(c (lambda_(1) - lambda_(2)))`
Hence, `E_(K_1) = 1.8 e V xx 1.6 xx 10^(-19) J`
and `E_(K_2) = 4.0 e V xx 4.0 xx 10^(-19) J`
Subtracting the given values, we get
`h = ((4.8 - 1.8) xx 1.6 xx 10^(-19) xx 8 xx 10^(-8) xx 7 xx 10^(-8))/(3 xx 110^(8) (8 xx 10^(-8) - 7 xx 10^(-8)))`
`- 6.57 xx 10^(-34) J - s`
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Knowledge Check

  • Ultraviolet light of wavelengths lambda_(1) and lambda_(2) when allowed to fall on hydrogen atoms in their ground state is found to liberate electrons with kinetic energy 1.8 eV and 4.0 eV respectively. Find the value of (lambda_(1))/(lambda_(2)) .

    A
    `(7)/(8)`
    B
    `(8)/(7)`
    C
    `(9)/(20)`
    D
    `(20)/(9)`
  • Ultraviolet light of wavelength lambda_(1) and lambda_(2) (with lambda_(2) gt lambda_(1) ) when allowed to fall on hydrogen atoms in their ground state is found to liberate electrons with kinetic energies E_(1) and E_(2) respectively. The value of the planck's constant can be found from the relation

    A
    `h=1/c(lambda_(2)-lambda_(1))(E_(1)-E_(2))`
    B
    `h=1/c(lambda_(2)+lambda_(1))(E_(1)+E_(2))`
    C
    `h=((E_(1)-E_(2))lambda_(1)lambda_(2))/(c(lambda_(2)-lambda_(1)))`
    D
    `h=((E_(1)+E_(2))lambda_(1)lambda_(2))/(c(lambda_(2)+lambda_(1)))`
  • The total energy of the electron in the hydrogen atom in the ground state is -13.6 eV. Which of the following is its kinetic energy in the first excited state?

    A
    13.6 eV
    B
    6.8 eV
    C
    3.4 eV
    D
    1.825 eV
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