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Oxygen exists as a gas, while sulphur ex...

Oxygen exists as a gas, while sulphur exists as a solid Why ?

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Oxygen , due to its small size is capable of forming `pi` bond and hence exist as `O=O` i.e. `O_(2)` molecule. `O_(2)` molecules are hend together by weak van der Waals forces of attaction, hence oxygen exists as a gas. On the other hand, sulphur due to its large size, is not capable of forming `pi-bonds`, rather each S-atom is `sp^(3)` hybridised and sulphur exists as `S_(8)` molecules. Due to high molecular mass of `S_(8)`, van der Waals forces of attaction between `S_(8)` molecules is large and sulphur exists as a solid.
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Knowledge Check

  • Statement-1 : At room temperature oxygen exists as a diatomic gas, where as sulphur exists as solid. Statement-2 : The catenated -O-O-O- chains are less stable as compared to O=O molecule.

    A
    Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-11
    B
    Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-12
    C
    Statement-1 is True, Statement-2 is False.
    D
    Statement-1 is False, Statement-2 is True.
  • Solid PCl_5 exists as

    A
    Dimer `P_(2)Cl_(10)`
    B
    `[PCl_(4)]^(+)[PCl_(6)]^(2-)`
    C
    `[PCl_(3)][Cl_(2)]`
    D
    `PCl_(5)` as mole
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