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1-Bromobutane is treated with sodium eth...

`1`-Bromobutane is treated with sodium ethoxide in ethanol. The major product obrained is

A

trans-but-`2`-ene

B

cis-But-`2`-ene

C

but-`1`-ene

D

`1`-ethoxybutane

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To determine the major product obtained when 1-bromobutane is treated with sodium ethoxide in ethanol, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactant is 1-bromobutane, which has the structure: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{CH}_2\text{Br} \] Here, the bromine (Br) is attached to the first carbon of the butane chain. 2. **Understand the Reaction Conditions**: Sodium ethoxide (NaOEt) is a strong base and ethanol (EtOH) is the solvent. Under these conditions, the reaction will likely proceed via an elimination mechanism (E2). 3. **Determine the Mechanism**: Since we are dealing with a strong base (sodium ethoxide), the elimination reaction will occur via the E2 mechanism. In E2, the base abstracts a proton (H) from a β-carbon (the carbon adjacent to the carbon with the leaving group), and the leaving group (Br) departs simultaneously. 4. **Identify β-Hydrogens**: In 1-bromobutane, the β-carbons are the second and third carbons in the chain. The β-hydrogens available for abstraction are: - From the second carbon: 2 hydrogens - From the third carbon: 2 hydrogens 5. **Elimination to Form Alkene**: The elimination can occur by removing a hydrogen from either the second or third carbon. - If we remove a hydrogen from the second carbon, we would form but-2-ene: \[ \text{CH}_3\text{CH}=\text{CH}\text{CH}_3 \] - If we remove a hydrogen from the third carbon, we would also form but-2-ene. 6. **Determine the Major Product**: Since both pathways lead to the formation of but-2-ene, we need to consider the stability of the alkene. But-2-ene can exist as two isomers: cis and trans. The trans isomer is generally more stable due to less steric hindrance. Therefore, the major product is trans-but-2-ene. 7. **Final Answer**: The major product obtained from the reaction of 1-bromobutane with sodium ethoxide in ethanol is **trans-but-2-ene**.

To determine the major product obtained when 1-bromobutane is treated with sodium ethoxide in ethanol, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactant is 1-bromobutane, which has the structure: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{CH}_2\text{Br} \] ...
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Knowledge Check

  • 2-Bromopentane is heated with potassium ethoxide in ethanol. The major product obtained is

    A
    pent-1-ene
    B
    cis pent-2-ene
    C
    trans-pent-2-ene
    D
    2-ethoxypentane
  • 2-bromopentane is heated with postassium ethoxide in ethano1 The major product obtained is .

    A
    Pentence -1
    B
    cis pentence -2
    C
    trans pentene-2
    D
    2-ethoxypentane
  • 2-Bromopentane is heated with EtO^(-)Na^(+) in ethanol. The major product obtained is

    A
    2-Ethoxpentance
    B
    Pent-1-ene
    C
    Isobutane
    D
    Pent-2-ene
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