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Which of the following generla rules for...

Which of the following generla rules for switching ligands or rotaing Fischer structures is incorrect?

A

An even number of switches results in no change in the configuration

B

An odd number of switches changes the configuration to that of the enantiomer

C

The structure cannot be rotated out of the plane of the paper

D

The structure can be rotated in the plane through `90^(@)`

Text Solution

Verified by Experts

The correct Answer is:
D

Any rotation of Fisher projections that interconverts horizontal and vertical ligands is not allowed. Hence, the structure can be rotated in the plane through `180^(@)` or its multiples but not through `90^(@)`
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Knowledge Check

  • Which of the following ligand does not as pi- acid ligand?

    A
    `N_(2)`
    B
    `CO`
    C
    `C_(2)H_(4)`
    D
    `O_(2)^(2-)`
  • Which of the following ligand does not as pi- acid ligand?

    A
    `N_(2)`
    B
    `CO`
    C
    `C_(2)H_(4)`
    D
    `O_(2)^(2-)`
  • Which of the following is/are bidentate chelating ligand ?

    A
    `[NH_(3)CH_(2)CH_(2)NH_(3)]^(2+)`
    B
    `NH(CH_(2)CO_(2)^(-))_(2)`
    C
    `H_(2)N-CH_(2)-underset(O)underset(||)C-O`
    D
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